Table 1. Benesi–Hildebrand Data for the 1:1 CT Complex at 25 °C.
Ca | Cd | A | CaCd/A | Ca + Cd | (CaCd/A) × 10–6 | (Ca + Cd) × 103 |
---|---|---|---|---|---|---|
ACN 25 °C | ||||||
0.001 | 0.005 | 0.791 | 6.32 × 10–6 | 0.006 | 6.32 | 6 |
0.001 | 0.0045 | 0.763 | 5.89 × 10–6 | 0.0055 | 5.89 | 5.5 |
0.001 | 0.004 | 0.716 | 5.58 × 10–6 | 0.005 | 5.58 | 5 |
0.001 | 0.0035 | 0.699 | 5.00 × 10–6 | 0.0045 | 5 | 4.5 |
0.001 | 0.003 | 0.665 | 4.51 × 10–6 | 0.004 | 4.51 | 4 |
0.001 | 0.0025 | 0.648 | 3.85 × 10–6 | 0.0035 | 3.85 | 3.5 |
0.001 | 0.002 | 0.618 | 3.23 × 10–6 | 0.003 | 3.23 | 3 |
0.001 | 0.001 | 0.489 | 2.04 × 10–6 | 0.002 | 2.04 | 2 |
MeOH 25 °C | ||||||
0.001 | 0.005 | 0.124 | 4.02 × 10–5 | 0.006 | 4.02 | 6 |
0.001 | 0.0045 | 0.120 | 3.7 × 10–5 | 0.0055 | 3.7 | 5.5 |
0.001 | 0.004 | 0.115 | 3.4 × 10–5 | 0.005 | 3.4 | 5 |
0.001 | 0.0035 | 0.110 | 3.0 × 10–5 | 0.0045 | 3.0 | 4.5 |
0.001 | 0.003 | 0.104 | 2.88 × 10–5 | 0.004 | 2.88 | 4 |
0.001 | 0.0025 | 0.098 | 2.55 × 10–5 | 0.0035 | 2.55 | 3.5 |
0.001 | 0.002 | 0.090 | 2.22 × 10–5 | 0.003 | 2.22 | 3 |
0.001 | 0.0015 | 0.085 | 1.76 × 10–5 | 0.0025 | 1.76 | 2.5 |
0.001 | 0.001 | 0.080 | 1.25 × 10–5 | 0.002 | 1.25 | 2 |