Table 7. Surface Area, Pore Size, Pore Volume, and Fractal Dimensions of Pores in Coal Samples.
| |
|
|
fractal
dimensions |
||||||||||||||
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| surface
area (m2/g) |
pore
volume (m3/g) |
pore
diameter (nm) |
region I (P/P0 = 0–0.5, D1) |
region
II (P/P0 = 0.5–1.0, D2) |
|||||||||||||
| sample no. | mBET | BJH | DFT | BJH | DFT | BJH | DFT | A1 | D1 = 3 + A1 | D1 = 3 + 3A1 | fitting equations | R12 | A2 | D2 = 3 + A2 | D2 = 3 + 3A2 | fitting equations | R22 |
| CG-1104 | 2.082 | 0.881 | 0.872 | 0.002 | 0.002 | 2.990 | 2.769 | –1.1511 | 1.8489 | –0.4533 | y = −0.8707x – 0.9356 | 0.99 | –0.4497 | 2.5503 | 1.6509 | y = −0.4497x-4.1590 | 0.80 |
| CG-1105 | 2.548 | 1.698 | 1.381 | 0.004 | 0.003 | 2.991 | 2.769 | –0.8707 | 2.1293 | 0.3879 | y = −0.9056x – 0.5654 | 0.95 | –0.3355 | 2.6645 | 1.9935 | y = −0.3355x-0.4652 | 0.75 |
| CG-1106 | 2.530 | 1.384 | 1.179 | 0.003 | 0.002 | 2.991 | 2.769 | –0.9056 | 2.0944 | 0.2832 | y = −0.8528x – 0.8092 | 0.99 | –0.5177 | 2.4823 | 1.4469 | y = −0.5177x – 0.3624 | 0.92 |
| CG-1107 | 9.782 | 2.916 | 0.299 | 0.007 | 0.006 | 4.474 | 2.769 | –0.8528 | 2.1472 | 0.4416 | y = −0.3944x – 0.9820 | 0.91 | –0.4736 | 2.5264 | 1.5792 | y = −0.4736x – 0.4073 | 0.83 |
| CG-1108 | 1.102 | 0.715 | 0.232 | 0.002 | 0.001 | 3.339 | 3.169 | –0.3944 | 2.6056 | 1.8168 | y = −0.7426x – 1.0652 | 0.82 | 4.777 | 2.7770 | 17.331 | y = 4.777x – 1.2254 | 0.41 |
| CG-1109 | 4.224 | 2.593 | 2.252 | 0.005 | 0.004 | 4.478 | 2.769 | –0.7426 | 2.2574 | 0.7722 | y = −0.3038x – 0.3900 | 0.99 | –0.3107 | 2.6893 | 2.0679 | y = −0.3107x – 1.0786 | 0.78 |
| CG-1110 | 2.870 | 1.400 | 1.217 | 0.003 | 0.002 | 2.991 | 2.769 | –0.3038 | 2.6962 | 2.0886 | y = −0.6729x – 0.7756 | 0.80 | –0.4441 | 2.5559 | 1.6677 | y = −0.4441x – 0.0983 | 0.87 |
| CG-1111 | 4.785 | 2.532 | 2.003 | 0.005 | 0.004 | 2.989 | 2.769 | –0.6729 | 2.3271 | 0.9813 | y = −1.3458x – 0.5501 | 0.90 | –0.4874 | 2.5126 | 1.5378 | y = −0.4874x – 0.3884 | 0.87 |
| CG-1112 | 3.975 | 2.042 | 1.771 | 0.004 | 0.003 | 3.336 | 2.769 | –1.3458 | 1.6542 | –1.0374 | y = −0.9577x – 0.6114 | 0.91 | –0.4751 | 2.5249 | 1.5747 | y = −0.4751x – 0.1453 | 0.81 |
| CG-1113 | 16.452 | 12.448 | 5.461 | 0.019 | 0.016 | 2.982 | 4.543 | –0.9577 | 2.0423 | 0.1269 | y = −1.7983x – 0.1246 | 0.88 | –0.4532 | 2.5468 | 1.6404 | y = −0.4532x – 0.2037 | 0.82 |
| CG-1114 | 11.192 | 7.485 | 3.169 | 0.011 | 0.011 | 2.988 | 3.169 | –1.7983 | 1.2017 | –2.3949 | y = −0.6761x – 0.1801 | 0.92 | –0.4828 | 2.5172 | 1.5516 | y = −0.4828x+0.4552 | 0.73 |
| CG-1115 | 4.114 | 4.838 | 1.969 | 0.010 | 0.006 | 3.736 | 4.543 | –0.6761 | 2.3239 | 0.9717 | y = −1.3154x – 0.3845 | 0.83 | –0.4947 | 2.5053 | 1.5159 | y = −0.4947x+0.2933 | 0.81 |
| CG-1116 | 5.412 | 2.270 | 4.831 | 0.005 | 0.005 | 2.991 | 0.750 | –1.3154 | 1.6846 | –0.9462 | y = −0.1466x + 0.0091 | 0.91 | –0.5067 | 2.4933 | 1.4799 | y = −0.5067x+0.0726 | 0.79 |
| CG-1117 | 10.614 | 6.460 | 6.313 | 0.012 | 0.012 | 2.985 | 3.627 | –0.1466 | 2.8534 | 2.5602 | y = −1.604x + 0.3096 | 0.70 | –0.2914 | 2.7086 | 2.1258 | y = −0.2914x+0.1408 | 0.92 |
| CG-1118 | 6.484 | 4.731 | 3.273 | 0.011 | 0.009 | 2.989 | 3.169 | –1.604 | 1.3960 | –1.8120 | y = −0.7609x – 0.1873 | 0.97 | –0.4386 | 2.5614 | 1.6842 | y = −0.4386x+0.2767 | 0.88 |
| CG-1119 | 4.632 | 3.093 | 1.937 | 0.007 | 0.005 | 3.154 | 3.169 | –0.7609 | 2.2391 | 0.7173 | y = −0.8087x – 0.9356 | 0.97 | –0.4537 | 2.5463 | 1.6389 | y = −0.4537x+0.1077 | 0.85 |
| CG-1120 | 4.817 | 3.127 | 2.463 | 0.008 | 0.006 | 2.988 | 3.627 | –0.8087 | 2.1913 | 0.5739 | y = −1.5703x – 0.3276 | 0.95 | –0.4261 | 2.5739 | 1.7217 | y = −0.4261x – 0.5107 | 0.77 |
| CG-1121 | 5.288 | 3.014 | 2.030 | 0.005 | 0.005 | 2.988 | 3.169 | –1.5703 | 1.4297 | –1.7109 | y = −0.9229x – 0.5767 | 0.99 | –0.4877 | 2.5123 | 1.5369 | y = −0.4877x – 0.1185 | 0.83 |
| CG-1122 | 4.441 | 2.833 | 2.463 | 0.007 | 0.001 | 3.338 | 3.169 | –0.9229 | 2.0771 | 0.2313 | y = −1.2095x – 0.7929 | 0.89 | –0.5032 | 2.4968 | 1.4904 | y = −0.5032x-0.113 | 0.81 |
| CG-1123 | 3.476 | 2.278 | 1.555 | 0.006 | 0.004 | 2.988 | 2.769 | –1.2095 | 1.7905 | –0.6285 | y = −1.4625x – 0.7365 | 0.88 | –0.5903 | 2.4097 | 1.2291 | y = −0.5903x – 0.2866 | 0.83 |