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. 2021 Dec 1;122(1):565–788. doi: 10.1021/acs.chemrev.1c00449

Scheme 128. B,N-Doped Pyrenoids.

Scheme 128

Reagents and conditions: (a)260 BBr3, i-Pr2EtN, o-DCB, 180 °C; (b)261 PhBCl2, Et3N, 1,2,4-trichlorobenzene, reflux, 36 h; (c) Pd(OAc)2, PCy3, Cs2CO3, o-xylene, reflux, overnight.