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. 2021 Dec 1;122(1):565–788. doi: 10.1021/acs.chemrev.1c00449

Scheme 186. Synthesis of Nitrogen-Containing Phenalenoids via Rhodium-Catalyzed Multiple C–H Bond Activation and Oxidative Annulation.

Scheme 186

Reagents and conditions: (a)364 [Cp*RhCl2]2, Cu(OAc)2, DMF, 100 °C, Ar, 24 h.