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. 2021 Dec 1;122(1):565–788. doi: 10.1021/acs.chemrev.1c00449

Scheme 193. Synthetic Routes to Boron-, Nitrogen-, and Sulfur-Doped PAHs.

Scheme 193

Reagents and conditions: (a)373n-BuLi, Et2O; (b) UV irradiation (Hg medium pressure lamp), I2, propylene oxide, cyclohexane; (c) (1) excess neat BBr3, (2) MesMgBr, toluene/THF; (d) (1) [n-Bu4N]F, THF, (2) (PPh3)Ru(cymene)Cl2, NH4PF6, (CH2Cl)2.