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. 2021 Dec 1;122(1):565–788. doi: 10.1021/acs.chemrev.1c00449

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© 2021 The Authors. Published by American Chemical Society

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Scheme 199 — Reagents and conditions: (a)³⁷⁹ corresponding boronic acid, KF, Pd₂(dba)₃, (t-Bu)₃P, THF, 80 °C, 30 min; (b) TMPMgCl·LiCl, THF, 2 h at 0 °C, then 16 h, rt; (c)³⁸⁰i-PrMgCl·LiCl, THF, 0 °C, 2 h.