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. 2021 Dec 1;122(1):565–788. doi: 10.1021/acs.chemrev.1c00449

Scheme 281. π-Extended Heterocycle-Fused Pyracylenes.

Scheme 281

Reagents and conditions: (a)498p-chloranil (1.0 equiv), DCM/TfOH (100/1), 0 °C, 10 min; (b) p-chloranil (2.0 equiv), DCM/TfOH (100:1), 0 °C, 10 min; (c)525 PhNH2, PdCl2, Et3N, DMSO, 90 °C, 8 h.