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. 2021 Dec 1;122(1):565–788. doi: 10.1021/acs.chemrev.1c00449

Scheme 296. peri-Naphtho-Fused Azepine Derivatives via Heptannulation.

Scheme 296

Reagents and conditions: (a)561 (254 nm, 2 × 8 W), DCM, rt; (b)562 Pd2(dba)3·CHCl3, BrettPhos, t-BuONa, toluene, 80 °C, 9 h; (c) anisole, TFA, toluene, 70 °C, 4 h.