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. 2021 Dec 1;122(1):565–788. doi: 10.1021/acs.chemrev.1c00449

Scheme 301. Syntheses of Fused 1,4- and 1,5-Diazocines.

Scheme 301

Reagents and conditions: (a)541 palladium(II) trifluoroacetate (30 mol %), AgOAc (6.0 equiv), pivalic acid, 160 °C, 48 h; (b)567 neat, 145–150 °C.