Scheme 348. Synthesis of Face-to-Face Dimers and Monomeric Gallium(III) Corrole Tapes.
Reagents and conditions: (a)650 (1) NaBH4, THF/MeOH, (2) GaCl3 (50 equiv), pyridine, reflux, workup; (b) R1ZnI·LiCl (20 equiv), TMSCl (40 equiv), THF, reflux.
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