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. 2021 Dec 1;122(1):565–788. doi: 10.1021/acs.chemrev.1c00449

Scheme 63. Synthesis of Dithiophene-Annulated Tetraarylperylenes.

Scheme 63

Reagents and conditions: (a)112 Pd(PPh3)4, bis(tributyltin)sulfide, toluene, reflux, 10 h; (b) 2-thienylmagnesium bromide, THF, 0 °C to rt, 12 h; (c) mesitylmagnesium bromide, THF, 0 °C to rt, 12 h.