Table 2. Effect of the QH-240 Amount as a Catalyst on the Reduction Efficiency of 4-NPa.
| entry | catalyst dosage (mg) | 4-NP conversion (%) | reduction time (min)b | 4-AP yield (%)c |
|---|---|---|---|---|
| 1 | 0 | 0 | 1 week | 0 |
| 2 | 0.05 | 75 | 60 | 53.1 |
| 3 | 0.1 | 87 | 15 | 78.8 |
| 4 | 0.2 | 98.3 | 6 | 89.5 |
| 5 | 0.5 | 99.5 | 4 | 92.1 |
| 6 | 1.0 | 99.8 | 3 | 93.4 |
Experimental conditions: [4-NP] = 0.05 mM, [NaBH4] = 10 mM, and T = 25 °C.
Reduction time = time after subtraction of induction time for each catalytic run.
The concentration changes of 4-AP obtained from the absorption changes in λmax = 300 nm.