Table 1. Triplet Parameters Obtained from the Simulations of the TR-EPR Spectra when Two Species are Present; Each Row Reports Two Sets of Parametersa.
| |D| | |E| | |E/D| | Px/Py/Pz | % | |
|---|---|---|---|---|---|
| P0 | 0.111 | 0.030 | 0.270 | 0.80:0.00:0.20 | 100 |
| P1 | 0.098 | 0.019 | 0.194 | 0.00:0.49:0.51 | >95 |
| 0.111 | n.d. | n.d. | n.d. | n.d. | |
| GdP1 | 0.098 | 0.019 | 0.194 | 0.00:0.39:0.61 | >95 |
| 0.111 | n.d. | n.d. | n.d. | n.d. | |
| 1 & Gd1 | 0.092 | 0.017 | 0.185 | 0.00:0.00:1.00 | 63 |
| 0.111 | 0.013 | 0.117 | 1.00:0.00:0.00 | 37 | |
| 2 | 0.090 | 0.008 | 0.089 | 0.07:0.00:0.93 | 62 |
| 0.100 | 0.024 | 0.240 | 0.93:0.07:0.00 | 38 | |
| Gd2 | 0.090 | 0.008 | 0.089 | 0.00:0.02:0.98 | 73 |
| 0.100 | 0.024 | 0.240 | 0.90:0.00:0.10 | 27 | |
| 3 | 0.074 | 0.016 | 0.216 | 0.79:0.21:0.00 | 100 |
| Gd3 | 0.070 | 0.016 | 0.229 | 0.49:0.51:0.00 | 100 |
Absolute values of the ZFS parameters |D| and |E| (cm–1); |E/D| ratio; triplet sublevel population (Px, Py, and Pz); relative amount of each spectral component (%). The g tensor for all is gxx = 2.006, gyy = gzz = 2.009. n.d. = not determined.