Table 2.
The Debye relaxation parameters, εs, εi, ε∞, and τi, for pure (100%) methanol, ethanol, 1-propanol, 2-propanol, and water are compared to the reported values in Refs. 16, 19, 20, and 39. In the triple Debye models, the values for εs, ε2, and τ1 are set to the parameters reported in Ref. 16.
| Model | Solute | Ref. | ε ∞ | ε s | ε 2 | ε 3 | τ1 (ps) | τ2 (ps) | τ3 (fs) |
|---|---|---|---|---|---|---|---|---|---|
| Triple Debye | Methanol | This work | 1.98 | 32.28 | 5.46 | 2.98 | 49.98 | 1.31 | 165 |
| (16) | 1.79 | 32.28 | 5.46 | 3.00 | 49.98 | 1.22 | 107 | ||
| (20) | 2.1 | 32.63 | 5.35 | 3.37 | 48 | 1.25 | 160 | ||
| Ethanol | This work | 2.06 | 24.51 | 4.45 | 2.73 | 163.6 | 2.16 | 231 | |
| (16) | 2.00 | 24.51 | 4.45 | 3.03 | 163.6 | 3.98 | 222 | ||
| (19) | 1.95 | 24.35 | 4.49 | 2.91 | 163 | 3.01 | 235 | ||
| (20) | 1.93 | 24.35 | 4.15 | 2.72 | 161 | 3.3 | 220 | ||
| 1-propanol | This work | 2.11 | 20.3 | 3.61 | 2.5 | 320.5 | 2.82 | 265 | |
| (16) | 2.07 | 20.3 | 3.61 | 2.64 | 320.5 | 8.15 | 202 | ||
| (20) | 1.97 | 20.44 | 3.43 | 2.37 | 316 | 2.9 | 200 | ||
| 2-propanol | This work | 2.07 | 19.42 | 3.65 | 2.55 | 350.9 | 4.24 | 256 | |
| (16) | 2.05 | 19.42 | 3.65 | 2.76 | 350.9 | 9.14 | 218 | ||
| Double Debye | Water | This work | 3.48 | 78.36 | 4.98 | 8.24 | 181 | ||
| (16) | 3.09 | 78.36 | 5.11 | 7.39 | 108 | ||||
| (19) | 3.49 | 78.36 | 5.16 | 7.89 | 181 | ||||
| (20) | 3.48 | 78.36 | 4.93 | 8.24 | 180 | ||||
| (39) | 4.1 | 78.8 | 6.6 | 10.06 | 180 | ||||
| Methanol | This work | 2.12 | 29.3 | 4.52 | 12.09 | 252 | |||
| (16) | 1.9 | 31.7 | 3.24 | 13.96 | 135 | ||||
| Ethanol | This work | 2.10 | 21.78 | 4.99 | 29.71 | 288 | |||
| (16) | 1.98 | 24.5 | 2.75 | 19.23 | 155 | ||||
| 1-propanol | This work | 2.12 | 17.8 | 2.5 | 44.09 | 319 | |||
| (16) | 2.04 | 20.40 | 2.49 | 35.79 | 138 | ||||
| 2-propanol | This work | 2.09 | 16.87 | 4.66 | 35.87 | 276 | |||
| (16) | 2.01 | 19.43 | 2.53 | 28.45 | 139 |