Decarbonylative addition of aldehydes to acetonea.
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Reaction conditions: 1 (0.1 mmol) and CsF (0.5 equiv.) in acetone (2a, 1.0 mL) were irradiated with a LED (405 nm, 3 W × 2) for 12 h at room temperature; isolated yields were given.
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Reaction conditions: 1 (0.1 mmol) and CsF (0.5 equiv.) in acetone (2a, 1.0 mL) were irradiated with a LED (405 nm, 3 W × 2) for 12 h at room temperature; isolated yields were given.