Table 1.
Detection rates for printing ink or photoinitiators in a survey of 362 samples representing different food/packaging combinations.
Foodstuff | Analyte | Detected Rate (%) | Min (ng/g) |
Max (ng/g) |
Mean (ng/g) |
SD (ng/g) |
GM (ng/g) |
---|---|---|---|---|---|---|---|
Cereal I: whole grains–rice flour (n = 59) |
BP | 100 | 17 | 108 | 38 | 20 | 34 |
4-MBP | 85 | <0.01 | 12 | 2.1 | 1.5 | 1.9 | |
4-OHBP | 5.1 | <0.51 | 33 | 17 | 15 | 12 | |
PBZ | 1.7 | <0.07 | 0.94 | 0.94 | - | 0.94 | |
Cereal II: whole grains–wheat and its products (n = 61) |
BP | 100 | 14 | 68 | 21 | 8.4 | 20 |
4-MBP | 100 | 1.2 | 66 | 4.2 | 8.3 | 2.8 | |
PBZ | 1.6 | <0.05 | 0.42 | 0.42 | - | 0.42 | |
Cereal III: whole grains–processed grain products (n = 60) |
BP | 100 | 22 | 1084 | 89 | 199 | 47 |
4-MBP | 100 | 0.90 | 12 | 2.6 | 1.8 | 2.3 | |
4-OHBP | 17 | <0.05 | 9.7 | 4.9 | 2.2 | 4.5 | |
M2BB | 8.3 | <0.29 | 17.3 | 5.3 | 6.9 | 2.8 | |
100% fresh fruit and vegetable juice (n = 14) | BP | 100 | 8.0 | 29 | 12 | 5.4 | 12 |
4-MBP | 100 | 0.20 | 0.50 | 0.30 | 0.08 | 0.30 | |
M2BB | 93 | 0.44 | 0.74 | 0.57 | 0.09 | 1.7 | |
PBZ | 79 | 0.14 | 2.3 | 0.48 | 0.63 | 1.5 | |
100% reconstituted fruit and vegetable juice (n = 63) | BP | 100 | 7.3 | 51 | 16 | 9.2 | 14 |
4-MBP | 87 | 0.11 | 1.5 | 0.20 | 0.20 | 0.15 | |
4-OHBP | 1.6 | 0.82 | 0.82 | 0.82 | -- | 0.05 | |
M2BB | 100 | 0.34 | 0.84 | 0.48 | 0.10 | 0.47 | |
PBZ | 47.6 | 0.14 | 1.6 | 0.38 | 0.36 | 1.2 | |
10% or more fruit and vegetable juice (n = 59) | BP | 100 | 5.2 | 37 | 13 | 5.5 | 12 |
4-MBP | 95 | 0.12 | 8.5 | 0.70 | 1.4 | 0.34 | |
M2BB | 100 | 0.37 | 0.81 | 0.54 | 0.11 | 0.52 | |
PBZ | 54 | 0.14 | 0.95 | 0.29 | 0.19 | 1.2 | |
Full-fat milk (n = 37) |
BP | 100 | 4.5 | 16 | 8.1 | 2.3 | 7.8 |
4-MBP | 30 | 0.34 | 101 | 28 | 32 | 0.17 | |
4-OHBP | 5.4 | 8.2 | 12 | 9.9 | 2.3 | 0.14 | |
M2BB | 35 | 0.22 | 0.46 | 0.29 | 0.09 | 0.14 | |
PBZ | 57 | 0.41 | 2.6 | 1.6 | 0.70 | 0.22 | |
Low-fat milk (n = 9) |
BP | 100 | 4.2 | 15 | 8.2 | 3.6 | 7.6 |
4-MBP | 22 | 21 | 150 | 85 | 91 | 0.16 | |
4-OHBP | 11 | 9.1 | 9.1 | 9.1 | -- | 0.17 | |
M2BB | 22 | 0.26 | 0.29 | 0.27 | 0.02 | 0.13 | |
PBZ | 78 | 0.60 | 2.3 | 1.6 | 0.65 | 0.55 |
BP = benzophenone; 4-MBP = 4-methylbenzophenone; 4-OHBP = 4-hydroxybenzophenone; PBZ = 4-phenylbenzophenone; M2BB = methyl-2-benzoylbenzoate; SD = standare deviation; GM = geometric mean.