Table 2.
Peak | Compounds | Rt (min) |
Molecular Formula | m/z Experimental | m/z Calculated | Ionization Mode | Error | Major Fragments (Intensity%) m/z |
---|---|---|---|---|---|---|---|---|
1 | Caffeicacid | 1.90 | C6H12O6 | 179.0558 | 179.0561 | N | 1.82 | 135 (6.7) |
2 | Gallicacid | 4.37 | C7H6O5 | 169.0143 | 169.0142 | N | −0.39 | 125 (85), 79 (100) |
3 | (epi)gallocatechin | 6.238 | C15H14O7 | 305.0668 | 305.0667 | N | −0.29 | 125 (3.69) |
4 | Catechin-O-hexoside | 8.222 | C21H24O11 | 451.1243 | 451.1246 | N | 0.51 | 289 (10.41) |
5 | o-Coumaric acid glucoside | 8.594 | C15H18O8 | 325.0928 | 325.0929 | N | 3.32 | 290 (15.02), 145 (8.31), 93 (57.82) |
6 | Quercetin 3-O-rhamnoside-7-O-glucoside | 8.718 | C27H30O1 | 609.1465 | 609.1461 | N | −0.53 | 462 (1.82) |
7 | Apigenin-6,8-C-dihexoside | 9.462 | C27H30O15 | 593.1523 | 593.1512 | N | −1.64 | 473 (53), 383 (26), 353 (44) |
8 | Epi-catechin | 9.895 | C15H14O6 | 289.0718 | 289.0718 | N | 0.23 | 245 (3.8) |
9 | Apigenin 6-C-pentoside-8-C-hexoside | 10.39 | C26H28O14 | 563.1413 | 563.1413 | N | −0.99 | 473 (1.1) |
10 | Rutin | 10.94 | C27H30O16 | 609.1468 | 609.1468 | N | −1.05 | 300 (26) |
11 | myricetin-O-hexoside | 11.507 | C21H20O13 | 479.0835 | 479.0831 | N | −0.55 | 317 (6.45) |
12 | Quercetin-O-rhamnoside | 11.817 | C21H20O11 | 447.0938 | 447.0933 | N | −1.14 | 300 (3.61), 173 (11.85), 111 (10.77) |
13 | Hyperoside | 12.313 | C21H20O12 | 463.0885 | 463.0882 | N | −0.36 | 300 (4.31), 271 (1.09) |
14 | Luteolin 8-C-glucoside | 12.994 | C21H20O11 | 447.0935 | 447.0938 | N | −0.38 | 429 (1.82) |
15 | Quercetin-3-O-galactoside | 13.118 | C21H20O12 | 463.0888 | 463.0882 | N | −1.25 | 301 (4.54) |
16 | Verbascoside | 13.181 | C27H28O17 | 623.1256 | 623.1254 | N | −0.26 | 461 (4.74) |
17 | Isorhamnetin-3-O-glucoside | 13.490 | C22H22O12 | 477.1043 | 477.1038 | N | −0.6 | 300 (5.18) |
18 | Naringenin-O-hexoside | 13.676 | C21H22O10 | 433.1134 | 433.114 | N | 0.91 | 271 (15.2) |
19 | Kaempferolrhamnoside | 14.792 | C21H20O10 | 431.0986 | 431.0984 | N | −0.5 | 285 (4.74) |
20 | Quercetin-3-O-glucoside | 14.91 | C21H20O12 | 463.0883 | 463.0882 | N | −0.02 | 300 (39) |
21 | Luteolin | 19.68 | C15H10O6 | 285.0406 | 285.0405 | N | −0.57 | 133 (2) |