Table 2.
Membrane | Membrane Characteristics | Fuel Cell Performance | Ref. | |||||
---|---|---|---|---|---|---|---|---|
WA (%) | IEC (meq. g−1) |
Ionic Conductivity (S cm−1) |
Methanol Permeability | Selectivity Ratio | Oxidative Stability | |||
PSF/MOF/Si nanocomposite | 16.50 | 0.86 | 0.017 @ 70°C | --- | --- | --- | OCV: 0.90 V; PD: 40.80 mW cm−2 @ 160 °C | [67] |
Crosslinked CNDs-SPPSU | 134 | 1.67 | 0.0563 @ 80 °C | --- | --- | --- | OCV: 1.0224 V @ 100% RH | [68] |
SPEESSA/sulfonic acid zeolite composite | 29.12 | 3.189 | 0.124 | --- | --- | --- | OCV: 0.91 V; PD: 0.45 W cm−2 @ 1.1 A cm−2 | [69] |
SPSU/NIMs-GO composite | 34.1 | 1.49 | 0.23 @ 75 °C | --- | --- | --- | OCV: 1.038 V; PD: 167.6 mW cm−2 @ 60 °C | [70] |
SPSU-LDH composite | 31 | 1.49 | 0.0137 @ 120 °C | --- | --- | --- | PD: 204.5 mW cm−2 @ 110 °C | [71] |
PSF-N-C3H6SO3H/ PSF-O-C3H6SO3H | 60 | 2.03 | 0.04666 | 2.65 × 10−8 cm2 s−1 | --- | 94.12% residual mass remains at 80 °C for 1 h in Fenton’s solution | --- | [72] |
PSU/SPANI/Nb2O5 nanocomposite | 17.6 | 1.50 | 0.0674 | --- | --- | 98.6% residual mass remains in Fenton’s solution | --- | [73] |
PSU-g-phosphonated polystyrene/SPSU composite | 23.07 | --- | 0.0172 @ 95 °C | 0.96 × 10−8 cm2 s−1 | --- | >95% residual mass remains at 25 °C for 120 h in Fenton’s solution | --- | [79] |
Phosphonated PSU | 6.6 | 2.75 | 0.0003 @ 160 °C | --- | --- | 87.7% residual mass remains for 70 h in Fenton’s solution | --- | [82] |
PA doped TDAP-g-PSU | --- | --- | 0.056 @ 160 °C | --- | --- | --- | OCV: 0.92 V; PD: 453 mW cm−2 @ 150 °C | [83] |
Poly(1-vinylimidazole)-g-PSU | 220.3 | --- | 0.127 @ 160 °C | --- | --- | --- | OCV: 0.98 V; PD: 559 mW cm−2 @ 160 °C | [84] |