Table 5.
Polymer | Carrier | Condition | Gas Pair | Separation Performance | Neat | References |
---|---|---|---|---|---|---|
Pebax | Aniline molecule (50 wt%) |
7 bar, 25 °C |
CO2, N2 Binary CO2, N2 (20%, 80%) |
α = 92.5; PCO2 = 151 Barrer α = 68; PCO2 = 123 Barrer |
α = 22.2; PCO2 = 75 Barrer α =19; PCO2 = 83 Barrer |
[122] |
PES | [DMAPAH][F]- Fluorion-based protic ionic liquids (FPILs) |
0.1 bar, 40 °C (water content 40%) |
CO2, N2 CO2, CH4 |
α = 774; PCO2 = 2572 Barrer α = 387; PCO2 = 2572 Barrer |
- | [123] |
PVA-PEG-GA (Glutaraldehyde) | (PETIM)– Amine-rich poly(ether imine) |
2 bar, 30 °C |
CO2, N2 | α = 56; PCO2 = 207.7 Barrer | - | [124] |
γ-Al2O3 | [Emim] [Tf2N]-ionic liquid | 1.5 bar, 30 °C |
CO2, N2 | α = 27; PCO2 = 23 GPU | - | [125] |
ILPPO | (Br-6-MPRD)– 1-bromohexyl-1 methylpiperidinium bromide |
1 bar, 25 °C |
CO2, N2 CO2, O2 |
α = 12.94; PCO2 = 907 Barrer α = 14.9; PCO2 = 907 Barrer |
α = 6.21; PCO2 = 70 Barrer α = 5.15; PCO2 = 70 Barrer |
[126] |
PES | ([bmim][PhO])1-butyl-3-methylimidazolium phenolate | 0.1 bar, 40 °C |
CO2, N2 | α = 135; PCO2 = 2020 Barrer (Dry) α = 127; PCO2 = 2540 Barrer (Wet) |
- | [3] |
PES | [DMAPAH] [MOAc] |
0.1 bar, 40 °C |
CO2, N2 | α = 66; PCO2 = 1391 Barrer | - | [128] |
PVDF | [Bmim][Ac] [Bmim][BF4] |
0.1 bar, 30 °C |
H2S/CH4 H2S/CO2 H2S/CH4 H2S/CO2 |
α = 142; PH2S = 5279 Barrer α = 11.9; PCO2 = 443 Barrer α = 40; PH2S = 3708 Barrer α = 3.5; PCO2 = 1056 Barrer |
[129] | |
PIM-COP | [C6mim][Tf2N] embedded | - | CO2, N2 | α = 30; PCO2 = 800 Barrer | α = 19; PCO2 = 7440 Barrer | [130] |