Table 2.
Some possible technologies and materials for 3D printing glass.
Technology | Polymerization of Monomer | Dispersant | Photoinitiator | Stabilizer | Absorber | SiO2 | References |
---|---|---|---|---|---|---|---|
SLA | 29.5 wt%HEMA 1+ 3.7 wt% PEGDA 2 |
— | 0.4 wt% DMPA 3 |
13.1 wt% DEDB 4+ 0.4wt%MEHQ 5 |
0.3 wt% Tinuvin 1130 |
53.7 wt% Aerosil OX50 | [39] |
28.1 wt%HEMA+3.7 wt% PEGDA | — | 0.4 wt% DMPA |
14.5 wt% DEDB |
0.02 wt% Sudan red G |
53.7 wt% Aerosil OX50 | [76] | |
DLP | 36.9 wt%HEMA+ 6.36 wt% TEGDA 6 |
19.0 wt% POE 7 |
0.2 wt% DPO 8 |
0.1 wt % hydroquinone |
— | 37.5wt% Aerosil OX50 | [34] |
60 vol%HEMA+ 10 vol%TEGDA |
30 vol% POE |
0.2 wt% Omnirad 819 9 |
0.1 wt% hydroquinone |
0.05 wt% Sudan Orange G |
37.5 vol% Aerosil OX50 | [35] | |
65 vol%HEMA+ 35 vol% TMPTA 10 |
— | 0.5 wt% Omnirad 819 |
0.5 wt% hydroquinone |
0.45 wt% Tinuvin 384-2 | 35 vol% Aerosil OX50 | [35] | |
TPP | 80 wt%HEMA | 20 wt% POE |
1 wt% BDK 11 |
— | — | 50 wt% Aerosil OX50 | [56] |
333 mg ETPTA 12+ 666 mgPEGDA |
— | 10 mg EMK 13 |
5mg hydroquinone |
— | 1600 mg colloidal silica solution | [57] | |
DIW | 79 wt%Tetraglyme | — | — | 1wt% PDMS | — | 21 wt%CAB-O-SIL EH-5 | [13] |
76 wt%Tetraglyme | — | — | 1wt% PDMS | — | 23 wt%CAB-O-SIL EH-5 | [13] | |
SL | 68 vol%HEMA+ 7 vol%TEGDA |
25 vol% POE |
0.5 wt% DMPA |
— | — | 40 vol% Aerosil OX50 | [33] |
68 vol%HEMA+ 7 vol%TEGDA |
25 vol% POE |
0.5 wt% DMPA |
— | — | 50 vol% silica nanopowder (Zandosil) |
[90] |
1 HEMA: hydroxyethyl methacrylate. 2 PEGDA: poly(ethylene glycol) diacrylate. 3 DMPA: 2,2-dimethoxy-2-phenylacetophenone. 4 DEDB: diethyl phthalate. 5 MEHQ: 4-methoxyphenol. 6 TEGDA: tetraethylene glycol diacrylate. 7 POE: phenoxyethanol. 8 DPO: diphenyl(2,4,6-trimethylbenzoyl) phosphine oxide. 9 Omnirad 819: phenylbis(2,4,6-trimethylbenzoyl)phosphine oxide. 10 TMPTA: trimethylolpropane ethoxylate triacrylate. 11 BDK: photoinitiator (2,2-Dimethoxy-2-phenylacetophenone). 12 ETPTA: trimethylolpropane ethoxylate triacrylate. 13 EMK: 4,4′-Bis(diethylamino)benzophenone.