Table 1. Activation Energies for Transport Properties.
|
ED (kJ/mol)f |
||||||
|---|---|---|---|---|---|---|
| xwa | Eη (kJ/mol)b | fragility m | Eκ (kJ/mol)c | TBA | DecA | DecA(H1)h |
| 0.0016 | 44.4 ± 0.7 | 98 ± 7 | 33.2 ± 1.8d (32.2 ± 1.5)e | 39.3 ± 0.3 | 41.0 ± 0.7 | 43.5 ± 0.6 |
| 0.153 | 40.3 ± 0.7 | 118 ± 8 | nd | 39.9 ± 0.3 | 38.4 ± 0.6 | 53.3 ± 2.7 |
| 0.222 | 36.0 ± 0.4 | 50 ± 30 | 29.7 ± 1.7 (29.3 ± 1.5) | ndi | nd | nd |
Water mole fraction.
Activation energy of the viscous flow.
Activation energy of conductivity (corrected for thermal expansion) according to:
Arrhenius’ law;
Modified Arrhenius’ law.
Self-diffusion activation energy.
H2O + H1 in DecA.
nd, not determined.