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. 2022 Jan 17;12(1):21–40. doi: 10.3390/jox12010003

Table 1.

Concentration of glyphosate and of its metabolite, AMPA, in various sources with relevance for animal toxicity.

Compound Sample Concentration Detection Method Ref.
Glyphosate Rainwater 6.1 µg/L LC–MSn [46]
Stream water 41 ng/L IC/MSn [47]
Groundwater 4 µg/L LC–MS [48]
Groundwater 21.2 µg/L UHPLC–MSn [49]
Groundwater 0.025 µg/L LC–MSn [50]
Lake water 4.52 µg/L HPLC–MSn [51]
Lake water 45 µg/L LC–MS [48]
Marine water 1.7 µg/L LC–MSn [52]
Suspended particulate matter 584 µg/kg UHPLC–MSn [53]
Water 17 µg/L UHPLC–MSn [54]
Suspended particulate matter 0.13 µg/L HPLC–MSn [51]
Sediment 20.34 µg/kg HPLC–MSn [51]
Sediment 3294 µg/kg UHPLC–MSn [53]
Sediment 1000 µg/kg LC–MS [48]
Soil 8105 µg/kg UHPLC–MSn [53]
Soil 1502 µg/kg UHPLC–MSn [55]
Soil 690 µg/kg LC–MS [48]
Air 0.48 ng/m3 HPLC-MS [56]
Air 0.24 ng/m3 HPLC-MS [56]
Air (application) 42.96 µg/m3 HPLC-FD [57]
Air (0–4 h after application) 0.1 µg/m3 HPLC-FD [57]
Air (4–8 h after application) 0.05 µg/m3 HPLC-FD [57]
Organic oat flour 11 µg/kg LC–MSn [58]
Oatmeal 1100 µg/kg LC–MSn [58]
Oat-based cereals 901 µg/kg LC–MSn [58]
Oat flour 554 µg/kg LC–MSn [58]
Wheat 670 µg/kg LC–MSn [59]
Durum wheat 421 µg/kg LC–MSn [60]
Breakfast cereal 291 µg/kg LC–MSn [61]
Soy protein isolate 105 µg/kg UHPLC–MSn [62]
Soy protein concentrate 850 µg/kg UHPLC–MSn [62]
Soybean 8800 µg/kg HPLC-FD [63]
Corn 1.6 µg/kg ELISA kit [64]
Coffee 26.32 µg/kg ELISA kit [64]
Pea 60 µg/kg LC–MSn [59]
Wine 18.9 µg/kg LC–MSn [61]
Beer 2.8 µg/kg ELISA kit [64]
Tea leaves 40.43 µg/kg ELISA kit [64]
Tea bag 728.2 µg/kg ELISA kit [64]
Bread 45.8 µg/kg LC–MSn [61]
Honey 220 µg/kg HPLC-FD [65]
Honey 49.8 µg/kg LC–MSn [66]
Cat and dog food 0.03 µg/kg ELISA kit [67]
Human urine 7.4 µg/L LC–MSn [68]
Human urine 1.36 µg/L LC–MSn [69]
Human urine 7.2 µg/L LC–MSn [70]
Human urine 5.6 µg/L LC–MSn [71]
Human urine 3.3 ng/L ELISA kit [72]
Human serum 1477 µg/mL LC–MSn [73]
Human serum 89 µg/mL LC–MSn [73]
AMPA Rainwater 5.8 µg/L LC–MS [46]
Groundwater 6.5 µg/L UHPLC–MSn [49]
Groundwater 0.65 µg/L LC–MSn [50]
Groundwater 11 µg/L LC–MS [48]
Lake water 0.90 µg/L HPLC–MSn [51]
Marine water 4.2 µg/L LC–MSn [52]
Water 4.5 µg/L UHPLC–MSn [54]
Suspended particulate matter 475 µg/kg UHPLC–MSn [53]
Suspended particulate matter 0.07 µg/L HPLC–MSn [51]
Sediment 7219 µg/kg UHPLC–MSn [53]
Sediment 15 µg/kg LC–MS [48]
Sediment 32.89 µg/kg HPLC–MSn [51]
Soil 38,939 µg/kg UHPLC–MSn [53]
Soil 2256 µg/kg UHPLC–MSn [55]
Soil 8 µg/kg LC–MS [48]
Air 0.06 ng/m3 HPLC-MS [56]
Air 0.02 ng/m3 HPLC-MS [56]
Oatmeal 40 µg/kg LC–MSn [58]
Oat-based cereals 25 µg/kg LC–MSn [58]
Oat flour 25 µg/kg LC–MSn [58]
Breakfast cereal 10 µg/kg LC–MSn [61]
Durum wheat 247 µg/kg LC–MSn [60]
Soy protein isolate 210 µg/kg UHPLC–MSn [62]
Soy protein concentrate 2710 µg/kg UHPLC–MSn [62]
Soybean 10,000 µg/kg HPLC-FD [63]
Wine 3.4 µg/kg LC–MSn [61]
Honey 100 µg/kg HPLC-FD [65]
Honey 50.1 µg/kg LC–MSn [66]
Human urine 1.53 µg/L LC–MSn [69]
Human serum 1.5 µg/mL LC–MSn [73]
Human serum 0.07 µg/mL LC–MSn [73]

Abbreviations: HPLC, high-performance liquid chromatography; UHPLC, ultra high-performance liquid chromatography; LC, liquid chromatography; IC, ion chromatography; MS, mass spectrometry; FD, fluorescence detector.