Table 5.
Regression coefficients, R2, p-value of lack of fit, the significance probability (p-value, t-ratio) of regression coefficients in final reduced second-order polynomial models of the final reduced models.
| Responses |
ΔH (%, Y1) |
ΔS (%, Y2) |
ΔCp (%, Y3) |
|||
|---|---|---|---|---|---|---|
| Coefficient | HIT1 | HIT2 | HIT1 | HIT2 | HIT1 | HIT2 |
| β0 | −1.43421 | 0.838606 | 0.023053 | 0.020568a | 0.096552 | 0.090432a |
| β1 | 0.00458 | −0.001248 | −0.000369 | −0.000202 | −0.000628 | 0.000334 |
| β2 | 0.11891 | 0.237095a | 0.000893 | 0.001140 | −0.001313 | – |
| β3 | 0.34548 | −0.100428 | – | −0.002012 | – | −0.020451a |
| 0.00032 | −0.000227a | 0.000007 | −0.000002 | 0.000014 | −0.000022a | |
| 0.00119 | −0.016667a | 0.000016 | −0.000057 | 0.000077a | – | |
| 0.00668 | −0.022102a | – | −0.000203a | – | −0.000365 | |
| β12 | −0.00160a | −0.001892a | −0.000022a | −0.000013 | −0.000049 | – |
| β13 | – | 0.004971a | – | 0.000061a | – | 0.000377a |
| β23 | −0.01100a | – | – | – | – | – |
| R2 | 0.618 | 0.953 | 0.478 | 0.907 | 0.374 | 0.898 |
| p-value | 0.018 | 0.000 | 0.026 | 0.000 | 0.196 | 0.000 |
| Lack of fit (p-value) | 0.064 | 0.162 | 0.621 | 0.284 | 0.051 | 0.362 |
| Main effects (p-values) | ||||||
| X1 | 0.951 | 0.895 | 0.722 | 0.190 | 0.111 | 0.629 |
| X2 | 0.134 | 0.005a | 0.374 | 0.311 | 0.083 | – |
| X3 | 0.247 | 0.147 | – | 0.072 | – | 0.001a |
| Quadratic effects (p-values) | ||||||
| X11 | 0.423 | 0.003a | 0.226 | 0.136 | – | 0.000a |
| X22 | 0.059 | 0.019a | 0.057 | 0.561 | – | – |
| X33 | 0.769 | 0.000a | – | 0.010a | – | 0.279 |
| Interaction effects (p-values) | ||||||
| X1X2 | 0.027a | 0.040a | 0.026a | 0.329 | 0.039a | – |
| X1X3 | – | 0.000a | – | 0.000a | – | 0.000a |
| X2X3 | 0.041a | – | – | – | – | – |
| Main effects (t-ratios) | ||||||
| X1 | −0.063 | −0.136 | −0.363 | −1.396 | 1.303 | 0.494 |
| X2 | 1.618 | 3.469 | 1.063 | 1.063 | 1.110 | – |
| X3 | 1.224 | −1.561 | – | −1.994 | – | −4.110 |
| Quadratic effects (t-ratios) | ||||||
| X11 | 0.831 | −3.743 | 1.266 | −1.609 | – | −4.780 |
| X22 | 2.102 | −2.753 | 2.075 | −0.599 | – | – |
| X33 | 0.302 | −5.256 | – | −3.083 | – | −1.125 |
| Interaction effects (t-ratios) | ||||||
| X1X2 | −2.558 | −2.328 | −2.487 | −1.020 | −1.223 | – |
| X1X3 | – | 7.340 | – | 5.767 | – | 7.180 |
| X2X3 | −2.313 | – | – | – | – | – |
| OP (X1, X2, X3) | ||||||
| OPHIT1 (68.5, 10, 2.56) | 1.1060 | – | 0.0154 | – | 0.0683 | – |
| OPHIT2 (40, 1.56, 2,5) | – | 0.7252 | – | 0.0100 | – | 0.0449 |
Abbreviation:β0 is a constant, βi, βii and βij are the linear, quadratic and interaction coefficients of the quadratic polynomial equation, respectively. i: Heating temperature generated via heat irradiation or heat ionization; ii: Time conducted for both treatments; ij: Mass of starting material for heat irradiation treatment or pH of buffer system for heat ionization.
Significant at p < 0.05.