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. 2022 Jan 26;13:502. doi: 10.1038/s41467-022-28184-0

Table 1.

Amino acid gas phase chiroptical properties and inducible ee values for an extent of reaction ξ = 0.9999.

Compound Transition A Transition B Transition C
λ/nm g ee (%)a λ/nm g ee (%)a λ/nm g ee (%)a
l-Alanine 244 −0.0039 |1.77| 214 0.0013 |0.61| 173 −0.0007 |0.32|
l-2-Aminobutyric acid 244 −0.0042 |1.90| 220 0.0029 |1.35| 176 −0.0005 |0.25|
l-Proline 236 −0.0021 |1.62| 200 0.0002 |0.20| 192 −0.0001 |0.08|
l-Valine 226 0.0031 |1.42| 176 −0.0004 |0.17|
l-Norvaline 245 −0.0016 |0.75| 219 0.0025 |1.14| 175 −0.0006 |0.27|
l-Isovaline 246 0.0017 |0.77| 203 −0.0008 |0.38| 179 0.0003 |0.12|
l-Leucine 247 −0.0019 |0.88| 221 0.0027 |1.22| 174 −0.0007 |0.30|

aThe lower limit of inducible ee is calculated using21: %ee(1(1ξ)g2)×100%, with ξ = 0.9999.