Table 3.
Comparison between the experimental and calculated Mössbauer parameters for anionic 8, anionic 9, and neutral 10. The sign of the experimental quadrupole splitting is undetermined.
| Complex | δ (mm/s) | ΔEQ (mm/s) | ||
|---|---|---|---|---|
| Exp. | Calc’d | Exp. | Calc’d | |
| 8 | 0.31 | 0.28 | |3.88| | + 3.97 |
| 9 | 0.18 | 0.29 | |0.93| | − 4.24 |
| 10 | 0.35 | 0.33 | |4.28| | + 4.34 |