Table 2. Use of the Diverse Classes of PCsHAT in the Forging of New Bonds.
| Bond formed/PCsHAT | Aromatic ketones | Anthraquinones | EY | DT | Ur | Sb-Oxo | TAC•2+ |
|---|---|---|---|---|---|---|---|
| C(sp3)–C(sp3) | √ | √ | √ | √ | √ | √ | |
| C(sp3)–C(sp2) | √ | √ | √ | √ | |||
| C(sp3)–C(sp) | √ | √ | √ | √ | |||
| C(sp2)–C(sp3) | √ | √ | √ | √ | √ | ||
| C(sp2)–C(sp2) | √ | √ | |||||
| C(sp2)–C(sp) | √ | ||||||
| C–N | √ | √ | |||||
| C–O | √ | √ | √ | √ | √ | ||
| C–S | √ | √ | √ | ||||
| C–Cl | √ | √ | |||||
| C–F | √ | √ | √ | ||||
| C–D | √ | ||||||
| Other bonds P–C, Si–Cl, Si–C, S–C | √ | √ | √ |