Table 3. Scale-up Production of Three Pharmaceutical Scaffolds Including Letrozole Precursor by Using 16N-PMR Assembly and Comparative Synthetic Performance of SMR and 4N-PMR.
| microreactor | yield of 2b [%]a | output of 2b [mg min–1] | yield of 2h [%]b | output of 2h [mg min–1] | yield of 2j [%]c | output of 2j [mg min–1] |
|---|---|---|---|---|---|---|
| SMR | 86 | 131.2 | 98 | 137.7 | 86 | 70.8 |
| 4N-PMR | 85 | 518.8 | 97 | 545.3 | 84 | 276.5 |
| 16N-PMR | 81 | 1971.0 | 92 | 2068.9 | 80 | 1053.2 |
Yield of isolated product.
Determined by 1H NMR spectroscopy using 1,3,5-trimethoxybenzene as an internal standard.
The yield was determined by GC.
