Substrate scope of the addition of C-nitrosos to 1^a.

^aConditions: 1 (0.2 mmol), 2a–o (0.2 mmol, 1 equiv.), 3 mL C₆H₆, N₂ atmosphere (glovebox). Isolated yields.

^bMixture of imine/enamine tautomers. See ESI for enamine characterization.

^{c 1}H NMR yield vs. 1,3,5-trimethoxybenzene internal standard = 0.2 M.