. 2021 Dec 29;13(5):1323–1334. doi: 10.1039/d1sc05749a

The energetic span (δE, in kcal mol⁻¹) for both the DAPCy configurations beginning from stereochemically different possible binding modes of allyl alcohol in the catalyst–substrate complex.

	Endo-re	Exo-si	Endo-si	Exo-re
(S,R,S)-DAPCy	14.1	10.6	11.2	13.0
(S,S,S)-DAPCy	15.1	12.3	13.0	12.6

The energetic span (δE, in kcal mol−1) for both the DAPCy configurations beginning from stereochemically different possible binding modes of allyl alcohol in the catalyst–substrate complex.