Table 1.
N° | Compound | % area | RIa | Identification |
---|---|---|---|---|
Monoterpenes hydrocarbons (26.59%) | ||||
1 | α-thujene | 0.65 | 944.2 | MS, RIb |
2 | α-pinene | 0.16 | 953.9 | MS, RIb |
3 | sabinene | 2.84 | 991.2 | MS, RIb |
4 | β-myrcene | 1.07 | 1005.9 | MS, RIb, Co-I |
5 | α-phellandrene | 0.48 | 1024.6 | MS, RIb |
6 | α-terpinolene | 5.02 | 1037.5 | MS, RIc |
7 | p-Cymene | 2.20 | 1045.8 | MS, RIb |
8 | 3-carene | 0.41 | 1055.8 | MS, RIb |
9 | γ-terpinene | 11.66 | 1080.3 | MS, RIb |
10 | α-terpinolene | 1.87 | 1110.4 | MS, RIb, Co-I |
11 | trans-allo-ocimene | 0.23 | 1150.5 | MS, RIb |
Oxygenated Monoterpenes (64.13%) | ||||
12 | 4-thujanol | 3.01 | 1089.2 | MS, RIb, |
13 | linalool | 0.55 | 1119.6 | MS, RIb |
14 | cis-sabinene hydrate | 16.72 | 1124.0 | MS, RIb |
15 | cis-β-terpineol | 0.02 | 1128.7 | MS, RIb, Co-I |
16 | cis-2-menthenol | 1.21 | 1147.6 | MS, RIb |
17 | trans-2-menthenol | 0.78 | 1165.7 | MS, RIb |
18 | pinocarvone | 0.02 | 1192.0 | MS, RIb |
19 | endo-borneol | 0.28 | 1194.8 | MS, RIb |
20 | 4-terpineol | 13.57 | 1205.5 | MS, RIb, Co-I |
21 | α-terpineol | 3.13 | 1218.3 | MS, RIb, Co-I |
22 | trans-piperitol | 0.30 | 1224.1 | MS, RIb |
23 | cis-piperitol | 0.38 | 1236.0 | MS, RIb |
24 | methyl carvacrol | 3.17 | 1269.9 | MS, RIb |
25 | linalyl acetate | 3.99 | 1277.1 | MS, RIb |
26 | thymol | 14.20 | 1314.5 | MS, RIb |
27 | carvacrol | 2.64 | 1324.0 | MS, RIb |
28 | geranyl acetate | 0.16 | 1406.2 | MS, RIb |
Sesquiterpenes (5.12%) | ||||
29 | caryophyllene | 3.56 | 1465.2 | MS, RIb |
30 | α-humulene | 0.32 | 1499.2 | MS, RIb |
31 | bicyclogermacrene | 1.24 | 1544.6 | MS, RIb |
Oxygenated Sesquiterpenes (0.47%) | ||||
32 | neryl acetate | 0.08 | 1387.5 | MS, RIb |
33 | spathulenol | 0.27 | 1631.7 | MS, RIb |
34 | caryophyllene oxide | 0.12 | 1640.5 | MS, RIb |
Others (2.55%) | ||||
35 | Cyclohexane, 1-methylene-4-(1-methylethenyl)- | 1.74 | 1051.9 | MS, RIb |
36 | benzene, 2-methoxy-4-methyl-1-(1-methylethyl)- | 0.81 | 1259.9 | MS, RIb |
Percentage of identified molecules | 98.86 |
a: Experimental retention index for non-polar column; b: bibliographic retention index for non-polar column, MS Mass spectra, Co-I Co-injection of standard