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. 2022 Feb 9;12:2152. doi: 10.1038/s41598-022-06251-2

Table 2.

Relative contribution (%) and structural indices calculated from spectral data of main C structures over chemical shift regions (ppm) of 13C CPMAS-NMR spectra of HA-LIG and HA-CYN.

Carboxyl-C Phenol-C Aryl-C O-Alkyl-C Methoxyl-C Alkyl-C Structural indexes
190–160 160–145 145–110 110–60 60–45 45–0 HB/HIa A/OAb ARMc LigRd
HA-LIG 6.1 9.6 33.0 12.8 9.8 28.7 2.49 2.27 1.02 1.06
HA-CYN 10.9 5.7 20.0 27.5 13.8 22.2 0.92 0.81 0.52 2.43

aHB/HI = hydrophobicity index = [Σ (0–45) + (110–160)/ Σ (45–60) + (60–110) + (160–190)].

bA/OA = alkyl/O-alkyl ratio (0–45)/(60–10).

cARM = aromaticity index [(110–160)/Σ (0–45) + (60–110)].

dLigR = Lignin ratio (45–60)/(140–160).