Table 4.
13C-NMR data of dimer-type pentacyclic triterpenoids isolated from Celastraceae species (2001–2021).
| C | D1 | D2 | D3 | D6 | D7 | D8 | D9 | D10 | D11 | D12 |
|---|---|---|---|---|---|---|---|---|---|---|
| 1 | 115.5 | 108.2 | 115.5 | 113.0 | 113.0 | 113.1 | 113.0 | 113.1 | 115.5 | 115.0 |
| 2 | 191.2 | 144.3 | 191.0 | 191.5 | 191.5 | 191.5 | 191.6 | 191.4 | 190.2 | 189.4 |
| 3 | 91.7 | 140.6 | 91.8 | 91.3 | 91.3 | 91.2 | 91.3 | 91.3 | 92.0 | 91.1 |
| 4 | 79.9 | 123.2 | 79.0 | 79.5 | 79.5 | 79.5 | 79.4 | 79.5 | 79.4 | 76.9 |
| 5 | 130.8 | 124.6 | 130.8 | 134.1 | 134.3 | 134.1 | 134.3 | 134.1 | 130.2 | 132.2 |
| 6 | 126.1 | 71.4 | 125.9 | 134.1 | 133.9 | 133.9 | 134.1 | 133.8 | 126.6 | 128.5 |
| 7 | 116.2 | 73.7 | 116.1 | 24.2 | 24.2 | 24.2 | 24.2 | 24.2 | 116.3 | 117.2 |
| 8 | 160.6 | 44.7 | 160.6 | 41.6 | 41.2 | 41.6 | 41.1 | 41.6 | 160.4 | 163.3 |
| 9 | 41.7 | 40.2 | 41.7 | 37.4 | 37.4 | 37.4 | 37.3 | 37.4 | 41.7 | 43.4 |
| 10 | 173.8 | 143.7 | 173.5 | 170.2 | 169.8 | 170.0 | 169.8 | 170.0 | 173.8 | 172.9 |
| 11 | 32.7 | 34.7 | 32.7 | 30.7 | 30.5 | 30.6 | 30.7 | 32.0 | 33.2 | 33.1 |
| 12 | 29.5 | 30.7 | 29.5 | 29.4 | 29.4 | 29.4 | 29.7 | 29.4 | 29.8 1 | 29.8 |
| 13 | 38.1 | 39.6 | 38.1 | 38.9 | 40.11 | 38.9 | 40.0 1 | 40.1 | 39.5 2 | 39.9 |
| 14 | 44.5 | 40.00 | 44.5 | 40.1 | 40.21 | 40.1 | 39.9 1 | 38.9 | 44.3 | 44.0 |
| 15 | 28.4 | 31.4 | 28.4 | 28.3 | 27.9 | 28.41 | 27.7 | 28.3 | 28.3 | 28.5 |
| 16 | 36.5 | 36.1 | 36.4 | 36.0 | 35.3 | 36.0 | 29.3 | 36.0 | 35.4 3 | 35.4 |
| 17 | 30.5 | 29.8 | 30.2 | 30.2 | 38.1 | 30.2 | 44.7 2 | 30.1 | 38.3 4 | 38.2 |
| 18 | 44.6 | 43.6 | 44.1 | 44.6 | 43.9 | 44.6 | 45.4 | 44.6 | 43.4 | 43.6 |
| 19 | 30.9 | 29.9 | 30.9 | 30.5 | 31.8 | 30.5 | 31.7 | 30.5 | 32.1 | 31.9 |
| 20 | 40.5 | 40.6 | 40.5 | 40.5 | 42.3 | 40.5 | 41.2 | 40.5 | 42.3 | 41.9 |
| 21 | 29.9 | 30.7 | 29.9 | 29.9 | 213.8 | 29.9 | 213.8 | 29.7 | 213.6 | 213.6 |
| 22 | 34.8 | 37.0 | 34.7 | 36.0 | 53.5 | 36.0 | 77.2 | 36.0 | 52.5 | 52.4 |
| 23 | 22.4 | 11.1 | 22.5 | 22.7 | 22.7 | 22.7 | 22.8 | 22.7 | 22.3 | 24.6 |
| 24 | ||||||||||
| 25 | 34.8 | 28.0 | 34.8 | 22.1 | 22.9 | 22.1 | 23.0 | 22.1 | 35.6 | 39.7 |
| 26 | 22.5 | 17.6 | 22.5 | 16.0 | 15.7 | 16.0 | 15.8 | 16.0 | 22.3 | 22.4 |
| 27 | 18.6 | 18.3 | 18.6 | 16.9 | 18.1 | 16.9 | 18.9 | 16.8 | 20.1 | 19.7 |
| 28 | 31.6 | 31.9 | 31.7 | 31.7 | 32.7 | 31.7 | 25.1 | 31.7 | 32.8 5 | 32.5 |
| 29 | 179.11 | 179.4 | 179.0 1 | 179.0 | 179.0 | 179.0 | ||||
| 30 | 32.9 | 31.7 | 31.9 | 32.3 | 15.2 | 32.3 | 14.9 | 32.3 | 15.2 6 | 15.1 |
| OCH3 | 51.72 | 51.3 | 51.5 2 | 51.7 | 51.7 | 51.7 | ||||
| 1′ | 110.4 | 109.5 | 110.4 | 110.5 | 110.6 | 110.4 | 110.6 | 110.4 | 109.6 | 108.8 |
| 2′ | 139.1 | 140.1 | 141.3 | 144.5 | 144.5 | 144.5 | 144.5 | 144.5 | 145.0 | 145.3 |
| 3′ | 136.2 | 138.9 | 137.0 | 138.3 | 138.3 | 138.4 | 138.2 | 138.4 | 137.6 | 137.4 |
| 4′ | 122.9 | 125.6 | 125.5 | 129.4 | 129.4 | 129.5 | 129.3 | 129.6 | 129.0 | 129.7 |
| 5′ | 127.9 | 123.6 | 127.2 | 123.3 | 123.3 | 123.4 | 123.7 | 123.4 | 126.0 | 125.3 |
| 6′ | 26.4 | 28.0 | 75.2 | 187.2 | 187.2 | 187.1 | 187.2 | 187.0 | 201.1 | 200.0 |
| 7′ | 18.5 | 18.5 | 21.8 | 126.3 | 126.3 | 126.3 | 126.3 | 126.3 | 37.6 | 37.4 |
| 8′ | 43.9 | 44.1 | 38.5 | 171.0 | 171.0 | 170.0 | 171.1 | 169.7 | 41.9 | 41.8 |
| 9′ | 36.8 | 36.9 | 37.6 | 40.1 | 40.1 1 | 39.9 | 40.1 | 39.7 | 37.1 | 37.0 |
| 10′ | 144.4 | 145.1 | 144.7 | 151.8 | 151.8 | 151.7 | 151.8 | 151.7 | 151.7 | 152.2 |
| 11′ | 33.9 | 34.3 | 33.8 | 34.2 | 34.3 | 34.4 | 34.3 | 34.6 | 32.9 | 33.2 |
| 12′ | 30.0 | 30.3 | 29.8 | 29.7 | 29.9 | 30.2 | 29.9 | 29.8 | 29.7 1 | 29.5 |
| 13′ | 38.9 | 39.0 | 38.9 | 39.0 | 39.0 | 40.2 | 39.0 | 40.1 | 39.4 2 | 39.2 |
| 14′ | 39.4 | 39.4 | 39.1 | 44.7 | 44.7 | 44.3 | 44.8 2 | 44.0 | 40.0 | 39.8 |
| 15′ | 28.9 | 29.1 | 29.0 | 28.5 | 28.6 | 28.3 1 | 28.6 | 28.2 | 28.0 | 27.7 |
| 16′ | 36.4 | 36.3 | 36.1 | 36.4 | 36.4 | 35.5 | 36.4 | 29.6 | 35.3 3 | 29.3 |
| 17′ | 30.6 | 30.2 | 29.3 | 30.5 | 30.5 | 38.2 | 30.5 | 44.91 | 38.2 4 | 45.0 |
| 18′ | 44.1 | 44.4 | 44.4 | 44.3 | 44.3 | 43.5 | 44.3 | 45.01 | 44.0 | 45.3 |
| 19′ | 30.4 | 29.5 | 30.5 | 31.0 | 31.0 | 32.0 | 31.1 | 30.1 | 31.8 | 31.7 |
| 20′ | 40.4 | 40.6 | 40.4 | 40.6 | 40.6 | 41.9 | 40.6 | 40.9 | 41.9 | 41.3 |
| 21′ | 30.3 | 30.7 | 30.3 | 29.9 | 29.7 | 213.7 | 29.7 | 213.6 | 214.1 | 214.0 |
| 22′ | 36.3 | 36.6 | 36.6 | 35.0 | 35.0 | 52.7 | 35.0 | 76.1 | 53.6 | 77.2 |
| 23′ | 10.9 | 10.9 | 10.6 | 13.4 | 13.4 | 13.4 | 13.4 | 13.4 | 13.0 | 13.3 |
| 24′ | ||||||||||
| 25′ | 27.2 | 27.2 | 31.5 | 37.7 | 37.7 | 38.7 | 37.6 | 38.9 | 26.2 | 26.5 |
| 26′ | 15.8 | 16.1 | 16.3 | 20.9 | 20.9 | 20.8 | 20.8 | 20.9 | 15.0 | 15.1 |
| 27′ | 17.2 | 17.3 | 17.4 | 18.6 | 18.5 | 20.0 | 18.6 | 20.8 | 18.2 | 19.0 |
| 28′ | 31.8 | 31.9 | 26.4 | 31.6 | 31.6 | 32.6 | 31.6 | 25.0 | 32.6 5 | 25.1 |
| 29′ | 178.7 1 | 179.8 | 178.7 1 | 179.2 | 179.3 | 179.4 | ||||
| 30′ | 32.7 | 30.8 | 32.7 | 32.9 | 32.9 | 15.1 | 33.0 | 14.8 | 15.1 6 | 14.8 |
| OCH3 | 51.5 2 | 51.6 | 51.7 2 | 51.6 | 51.6 | 51.7 | ||||
| OCH3 | 55.4 | |||||||||
| Ref | [133] | [134] | [133] | [135] | [136] | [136] | [137] | [137] | [136] | [136] |
| C | D13 | D14 | D15 | D16 | D17 | D18 | D19 | D20 | D21 | D22 |
| 1 | 114.0 | 108.3 | 49.1 | 108.6 | 107.8 | 107.6 | 109.1 | 108.8 | 111.4 | 108.9 |
| 2 | 191.2 | 144.4 | 193.1 | 146.5 | 142.0 | 141.4 | 144.9 | 141.1 | 149.6 | 137.9 |
| 3 | 91.3 | 140.7 | 192.1 | 141.7 | 137.7 | 141.4 | 142.7 | 141.7 | 143.2 | 142.2 |
| 4 | 79.1 | 123.2 | 60.5 | 123.0 | 121.4 | 120.8 | 122.3 | 121.3 | 126.0 | 121.1 |
| 5 | 134.7 | 124.7 | 131.7 | 125.4 | 124.3 | 124.4 | 125.7 | 126.0 | 124.1 | 125.0 |
| 6 | 135.9 | 71.5 | 28.2 | 124.3 | 124.4 | 123.6 | 124.3 | 124.2 | 187.7 | 124.3 |
| 7 | 68.5 | 74.5 | 18.3 | 128.6 | 128.4 | 127.7 | 128.7 | 129.2 | 126.1 | 128.8 |
| 8 | 51.7 | 45.1 | 45.7 | 45.4 | 45.6 | 44.8 | 44.4 | 45.6 | 171.2 | 45.5 |
| 9 | 41.1 | 40.3 | 37.4 | 37.5 | 37.2 | 36.3 | 37.2 | 37.2 | 40.05 | 37.0 |
| 10 | 168.7 | 143.7 | 148.8 | 143.6 | 142.2 | 141.3 | 143.3 | 142.8 | 151.7 | 141.8 |
| 11 | 31.2 | 34.8 | 31.0 | 31.0 | 31.1 | 30.4 | 30.5 | 31.2 | 34.12 | 31.9 |
| 12 | 29.4 | 30.4 | 29.7 | 30.0 | 30.4 | 29.2 | 38.2 | 30.5 | 28.5 | 30.5 |
| 13 | 39.4 | 39.7 | 39.6 | 38.9 | 39.3 | 38.1 | 38.8 | 38.9 | 39.0 | 38.8 |
| 14 | 41.8 | 40.0 | 39.3 | 39.0 | 39.2 | 38.2 | 45.4 | 39.0 | 44.6 | 39.0 |
| 15 | 31.0 | 31.7 | 28.9 | 28.1 | 28.1 | 27.3 | 28.1 | 28.2 | 29.8 | 28.1 |
| 16 | 36.2 | 36.2 | 36.4 | 35.5 | 36.0 | 35.6 | 35.4 | 36.0 | 35.4 | 36.2 |
| 17 | 30.0 | 29.8 | 30.3 | 30.3 | 30.6 | 29.6 | 30.3 | 30.4 | 30.5 | 30.4 |
| 18 | 44.8 | 43.6 | 44.5 | 44.4 | 44.5 | 43.7 | 43.6 | 44.5 | 44.3 | 44.4 |
| 19 | 30.6 | 30.0 | 30.4 | 30.6 | 30.0 | 29.2 | 30.0 | 30.1 | 30.8 | 31.0 |
| 20 | 40.61 | 40.7 | 40.7 | 40.6 | 40.5 | 39.7 | 40.5 | 40.5 | 40.4 | 40.5 |
| 21 | 29.8 | 31.6 | 30.0 | 29.7 | 29.9 | 29.8 | 29.9 | 29.9 | 29.9 | 29.4 |
| 22 | 35.8 | 37.1 | 36.7 | 36.5 | 36.4 | 36.1 | 35.9 | 36.4 | 36.4 | 36.3 |
| 23 | 22.4 | 11.1 | 9.0 | 10.8 | 10.8 | 9.9 | 10.7 | 10.7 | 13.1 | 10.9 |
| 24 | ||||||||||
| 25 | 24.0 | 28.0 | 22.3 | 22.2 | 16.8 | 21.6 | 22.1 | 22.3 | 37.7 | 22.3 |
| 26 | 16.5 | 17.8 | 16.0 | 17.0 | 22.2 | 16.0 | 16.8 | 16.9 | 20.8 | 16.8 |
| 27 | 17.4 | 18.3 | 17.2 | 17.5 | 17.4 | 16.6 | 17.3 | 17.4 | 18.3 | 17.4 |
| 28 | 31.7 | 32.00 | 31.9 | 31.8 | 31.8 | 31.0 | 31.7 | 31.8 | 31.6 | 31.8 |
| 29 | 179.0 | 179.4 | 179.2 | 179.3 | 179.1 | 178.3 | 179.1 | 179.1 | 178.8 | 179.1 |
| 30 | 32.4 | 32.00 | 31.9 | 32.2 | 32.1 | 31.3 | 32.1 | 32.1 | 32.7 | 32.1 |
| OCH3 | 51.7 | 51.6 | 51.6 | 51.6 | 51.5 | 50.7 | 51.6 | 51.5 | 51.5 | 51.5 |
| 1′ | 110.6 | 107.9 | 60.8 | 92.7 | 87.1 | 90.3 | 92.2 | 90.5 | 92.7 | 139.9 |
| 2′ | 144.2 | 141.6 | 24.4 | 38.6 | 41.8 | 44.6 | 36.3 | 45.8 | 38.4 | 36.0 |
| 3′ | 138.0 | 139.1 | 41.3 | 128.7 | 124.2 | 124.4 | 128.2 | 128.2 | 128.1 | 74.2 |
| 4′ | 129.3 | 122.0 | 39.8 | 140.5 | 151.2 | 141.2 | 140.6 | 140.6 | 140.6 | 90.1 |
| 5′ | 123.5 | 124.1 | 44.4 | 97.1 | 84.3 | 89.4 | 96.8 | 89.7 | 96.8 | 134.6 |
| 6′ | 187.2 | 124.3 | 25.1 | 38.1 | 35.2 | 35.2 | 38.9 | 84.6 | 39.1 | 30.0 |
| 7′ | 126.2 | 128.6 | 36.1 | 43.7 | 45.3 | 39.9 | 45.5 | 41.4 | 43.3 | 49.4 |
| 8′ | 171.0 | 45.8 | 151.4 | 36.0 | 38.9 | 35.8 | 32.7 | 29.7 | 34.8 | 29.9 |
| 9′ | 40.2 | 37.5 | 42.5 | 32.7 | 39.0 | 29.7 | 31.1 | 29.6 | 33.0 | 39.8 |
| 10′ | 151.9 | 143.8 | 36.2 | 40.1 | 32.9 | 43.0 | 39.4 | 43.2 | 39.3 | 42.6 |
| 11′ | 34.2 | 31.7 | 34.8 | 151.0 | 151.9 | 150.6 | 151.1 | 140.1 | 150.8 | 150.7 |
| 12′ | 29.9 | 30.0 | 21.9 | 108.7 | 108.4 | 108.0 | 108.6 | 119.1 | 108.8 | 108.6 |
| 13′ | 39.0 | 38.9 | 30.0 | 19.9 | 19.4 | 20.1 | 19.9 | 169.7 | 20.0 | 20.5 |
| 14′ | 44.7 | 39.1 | 16.7 | 19.1 | 20.3 | 17.8 | 19.1 | 19.0 | 19.1 | 17.1 |
| 15′ | 28.6 | 30.4 | 111.8 | 12.6 | 22.9 | 10.7 | 12.5 | 14.4 | 12.4 | 13.9 |
| 16′ | 36.4 | 36.1 | ||||||||
| 17′ | 30.5 | 30.5 | ||||||||
| 18′ | 44.3 | 44.5 | ||||||||
| 19′ | 30.9 | 29.4 | ||||||||
| 20′ | 40.5 1 | 40.6 | ||||||||
| 21′ | 29.8 | 31.6 | ||||||||
| 22′ | 35.0 | 36.6 | ||||||||
| 23′ | 13.4 | 10.8 | ||||||||
| 24′ | ||||||||||
| 25′ | 37.6 | 22.3 | ||||||||
| 26′ | 20.9 | 17.2 | ||||||||
| 27′ | 18.4 | 17.3 | ||||||||
| 28′ | 31.6 | 31.8 | ||||||||
| 29′ | 179.0 | 179.6 | ||||||||
| 30′ | 32.8 | 31.6 | ||||||||
| OCH3 | 51.7 | 51.4 | ||||||||
| Ref | [136] | [134] | [75] | [138] | [138] | [138] | [138] | [138] | [138] | [138] |
| C | D23 | D24 | D25 | D26 | D27 | D28 | D30 | D31 | D32 | D33 |
| 1 | 107.6 | 108.2 | 116.0 | 114.8 | 116.5 | 114.6 | 115.4 | 108.2 | 115.9 | 114.9 |
| 2 | 145.8 | 142.4 | 187.8 | 187.3 | 193.3 | 189.6 | 191.0 | 144.4 | 190.8 | 189.6 |
| 3 | 136.2 | 138.6 | 92.2 | 90.8 | 93.1 | 91.3 | 91.8 | 140.6 | 92.0 | 90.7 |
| 4 | 122.7 | 121.6 | 79.1 | 76.9 | 79.2 | 77.2 | 79.1 | 123.0 | 79.4 | 77.2 11 |
| 5 | 124.0 | 124.6 | 130.3 | 131.7 | 130.7 | 131.3 | 130.6 | 124.7 | 130.5 | 132.1 |
| 6 | 124.2 | 124.2 | 126.6 | 128.8 | 126.7 | 129.8 | 126.1 | 71.3 | 125.9 | 128.7 |
| 7 | 128.3 | 128.6 | 116.0 | 117.3 | 115.7 | 117.2 | 116.2 | 74.2 | 116.2 | 116.9 |
| 8 | 45.6 | 45.6 | 161.8 | 164.4 | 162.4 | 164.8 | 160.8 | 45.0 | 161.2 | 164.5 |
| 9 | 37.3 | 37.3 | 41.9 | 43.8 | 42.0 | 43.9 | 41.8 | 40.3 | 41.6 | 44.1 |
| 10 | 143.0 | 142.7 | 174.4 | 173.4 | 174.8 | 173.8 | 173.8 | 143.9 | 173.4 | 173.3 |
| 11 | 31.1 | 31.1 | 32.8 | 32.9 | 33.4 | 32.88 | 32.8 | 34.6 | 32.8 | 32.9 |
| 12 | 30.1 | 30.0 | 29.2 | 29.4 | 29.3 | 29.3 | 29.5 | 30.3 | 29.2 | 29.9 1 |
| 13 | 39.0 | 38.9 | 38.1 | 38.9 | 38.0 | 38.5 | 38.2 | 39.6 | 37.9 | 38.7 |
| 14 | 38.9 | 39.0 | 44.6 | 44.3 | 44.6 | 44.4 | 44.5 | 39.9 | 44.6 | 44.4 |
| 15 | 28.2 | 28.2 | 28.3 | 28.6 | 28.4 | 28.6 | 28.3 | 28.5 | 28.5 | 28.6 2 |
| 16 | 36.4 | 36.0 | 36.3 | 36.2 | 36.2 | 36.2 | 36.4 | 36.1 | 36.3 | 36.4 |
| 17 | 30.4 | 30.4 | 30.5 | 30.4 | 30.4 | 30.4 | 30.4 | 29.9 | 30.5 | 30.6 |
| 18 | 44.5 | 44.5 | 44.0 | 44.1 | 44.1 | 44.1 | 44.2 | 43.9 | 44.2 | 44.4 3 |
| 19 | 30.6 | 30.6 | 30.9 | 30.6 | 31.0 | 30.7 | 30.9 | 30.7 | 30.6 | 30.9 4 |
| 20 | 40.5 | 40.5 | 40.0 | 40.3 | 39.7 | 40.1 | 40.5 | 40.7 | 40.3 | 40.5 5 |
| 21 | 30.0 | 29.8 | 29.6 | 29.8 | 29.7 | 29.4 | 29.8 | 29.7 | 29.4 | 29.9 6 |
| 22 | 36.0 | 36.4 | 34.6 | 34.8 | 34.3 | 34.4 | 34.8 | 36.9 | 34.7 | 34.8 7 |
| 23 | 11.0 | 10.9 | 22.2 | 24.5 | 22.2 | 24.4 | 22.0 | 11.1 | 22.4 | 24.2 |
| 24 | ||||||||||
| 25 | 22.3 | 22.2 | 34.8 | 39.2 | 35.2 | 39.1 | 34.8 | 28.2 | 37.5 | 39.3 |
| 26 | 16.9 | 16.9 | 22.4 | 22.5 | 18.4 | 18.6 | 22.3 | 17.1 | 22.0 | 22.4 |
| 27 | 17.5 | 17.4 | 18.8 | 18.5 | 22.2 | 22.2 | 18.7 | 18.4 | 18.9 | 18.3 8 |
| 28 | 31.8 | 31.8 | 31.6 | 31.5 | 31.4 | 31.4 | 31.6 | 31.8 | 31.6 | 31.6 9 |
| 29 | 179.1 | 179.1 | 184.5 | 184.3 | 182.4 | 183.5 | 178.7 | 179.4 | 184.4 | 178.9 10 |
| 30 | 32.1 | 32.1 | 32.6 | 32.4 | 31.8 | 32.4 | 32.7 | 31.3 | 32.7 | 32.8 |
| OCH3 | 51.5 | 51.5 | 51.7 | 51.6 | 51.6 | |||||
| 1′ | 135.4 | 142.7 | 111.2 | 110.8 | 36.2 | 37.9 | 108.8 | 108.2 | 110.4 | 110.7 |
| 2′ | 36.5 | 34.5 | 144.4 | 145.0 | 18.7 | 18.8 | 140.8 | 142.1 | 144.7 | 144.2 |
| 3′ | 74.2 | 78.8 | 137.5 | 137.4 | 40.4 | 41.3 | 136.5 | 138.0 | 138.2 | 138.5 |
| 4′ | 89.9 | 86.1 | 127.2 | 128.3 | 33.0 | 33.1 | 121.3 | 121.0 | 129.5 | 128.2 |
| 5′ | 137.7 | 138.0 | 124.4 | 123.6 | 49.8 | 49.2 | 126.0 | 125.7 | 23.0 | 124.0 |
| 6′ | 32.1 | 35.0 | 192.0 | 189.9 | 35.7 | 35.9 | 124.0 | 124.4 | 187.5 | 187.8 |
| 7′ | 49.6 | 46.3 | 126.0 | 126.1 | 197.1 | 198.4 | 129.4 | 128.9 | 126.0 | 126.2 |
| 8′ | 29.7 | 30.0 | 171.4 | 171.0 | 126.0 | 125.9 | 45.5 | 45.9 | 171.4 | 171.5 |
| 9′ | 39.6 | 38.5 | 40.3 | 40.0 | 150.3 | 151.3 | 37.4 | 37.6 | 40.0 | 39.9 |
| 10′ | 42.6 | 34.7 | 150.1 | 151.1 | 37.7 | 37.7 | 142.8 | 141.9 | 151.9 | 151.1 |
| 11′ | 150.7 | 151.2 | 34.0 | 33.8 | 112.6 | 112.1 | 30.6 | 31.1 | 34.2 | 34.2 |
| 12′ | 108.7 | 108.5 | 29.3 | 29.1 | 147.2 | 147.0 | 30.0 | 30.0 | 29.9 | 29.6 1 |
| 13′ | 20.4 | 20.4 | 38.9 | 38.5 | 139.8 | 139.4 | 38.9 | 39.0 | 39.0 | 39.0 |
| 14′ | 17.1 | 19.3 | 44.7 | 44.6 | 114.9 | 115.8 | 39.0 | 39.1 | 44.6 | 44.7 |
| 15′ | 14.0 | 22.3 | 28.3 | 28.4 | 32.8 | 32.5 | 28.4 | 29.9 | 28.5 | 28.5 2 |
| 16′ | 36.2 | 36.2 | 21.3 | 21.3 | 36.0 | 36.1 | 36.3 | 36.4 | ||
| 17′ | 30.4 | 30.3 | 23.3 | 23.2 | 30.6 | 30.5 | 30.4 | 30.6 | ||
| 18′ | 44.1 | 44.1 | 44.5 | 44.5 | 44.0 | 44.3 3 | ||||
| 19′ | 30.5 | 30.7 | 31.0 | 30.7 | 31.1 | 30.8 4 | ||||
| 20′ | 39.7 | 40.1 | 40.4 | 40.6 | 40.2 | 40.4 5 | ||||
| 21′ | 29.5 | 29.7 | 29.7 | 30.0 | 29.3 | 29.7 6 | ||||
| 22′ | 34.4 | 34.5 | 36.4 | 36.7 | 34.4 | 34.7 7 | ||||
| 23′ | 12.9 | 13.2 | 10.8 | 11.0 | 13.2 | 12.8 | ||||
| 24′ | ||||||||||
| 25′ | 36.8 | 37.5 | 22.5 | 22.2 | 34.7 | 38.0 | ||||
| 26′ | 20.7 | 20.9 | 16.9 | 17.1 | 20.9 | 20.9 | ||||
| 27′ | 18.6 | 18.8 | 17.4 | 17.6 | 18.8 | 18.2 8 | ||||
| 28′ | 31.3 | 31.5 | 31.8 | 31.8 | 32.5 | 31.6 9 | ||||
| 29′ | 183.6 | 184.3 | 178.7 | 179.5 | 183.6 | 178.7 10 | ||||
| 30′ | 32.4 | 32.2 | 32.1 | 32.1 | 32.8 | |||||
| OCH3 | 51.6 | 51.5 | 32.4 | 51.6 | ||||||
| Ref | [138] | [138] | [139] | [139] | [139] | [139] | [133] | [134] | [139] | [136] |
| C | D34 | D35 | D36 | D37 | D38 | D39 | D40 | D41 | D42 | D43 |
| 1 | 116.0 | 114.9 | 116.0 | 109.0 | 111.4 | 115.8 | 114.7 | 115.5 | 115.5 | 115.0 |
| 2 | 190.4 | 189.5 | 190.4 | 145.1 | 149.7 | 191.1 | 189.4 | 190.2 | 190.3 | 189.5 |
| 3 | 91.8 | 90.6 | 91.8 | 142.8 | 143.3 | 91.9 | 91.0 | 92.0 | 92.0 | 91.0 |
| 4 | 79.4 | 76.9 | 79.3 | 122.5 | 125.2 | 78.8 | 77.3 | 79.3 | 79.4 | 76.8 |
| 5 | 130.9 | 132.0 | 130.9 | 125.7 | 122.4 | 131.1 | 131.8 | 130.3 | 130.3 | 132.1 |
| 6 | 126.1 | 128.7 | 126.2 | 124.6 | 187.5 | 126.1 | 128.8 | 126.6 | 126.6 | 128.7 |
| 7 | 116.2 | 116.8 | 116.4 | 128.3 | 126.2 | 116.4 | 117.2 | 116.3 | 116.3 | 117.3 |
| 8 | 160.2 | 164.6 | 159.9 | 44.9 | 170.2 | 159.5 | 164.4 | 160.3 | 160.1 | 163.0 |
| 9 | 41.5 | 44.2 | 41.4 | 39.4 | 39.3 | 41.3 | 43.9 | 41.7 | 41.6 | 43.7 1 |
| 10 | 173.2 | 173.4 | 173.2 | 143.3 | 151.7 | 173.4 | 173.2 | 173.7 | 173.8 | 173.0 |
| 11 | 33.3 | 32.8 | 33.5 | 31.7 | 34.3 | 33.5 | 32.8 | 33.2 | 33.4 | 33.3 |
| 12 | 29.8 1 | 29.5 | 29.9 1 | 29.9 | 30.2 | 30.0 | 29.8 | 29.9 1 | 29.9 1 | 29.9 |
| 13 | 39.5 | 38.6 | 39.5 | 38.3 | 39.9 | 39.5 | 38.6 | 39.4 | 39.4 | 39.8 |
| 14 | 44.2 | 44.4 1 | 43.9 | 32.8 | 44.3 | 44.1 | 44.4 | 44.3 | 44.0 | 43.61 |
| 15 | 28.3 | 28.6 | 28.1 | 27.5 | 28.4 | 28.3 | 28.6 | 28.3 | 28.0 | 28.2 |
| 16 | 35.5 | 36.4 | 29.5 2 | 35.3 | 35.6 | 29.7 | 36.4 | 35.4 | 29.5 | 29.5 |
| 17 | 38.2 | 30.5 | 44.7 | 35.4 | 38.2 | 39.0 | 30.5 | 38.2 | 44.7 | 45.0 |
| 18 | 43.4 | 44.1 | 44.9 | 43.5 | 43.5 | 43.8 | 44.2 | 43.4 | 44.9 | 44.8 |
| 19 | 32.2 | 30.8 | 32.1 | 31.0 | 32.0 | 32.1 | 30.9 | 32.1 | 32.1 | 31.9 |
| 20 | 41.9 | 40.4 | 40.8 | 40.1 | 41.9 | 41.8 | 40.5 | 41.9 | 40.8 | 40.9 |
| 21 | 213.6 | 29.9 | 213.5 | 214.3 | 213.7 | 213.6 | 29.8 | 213.6 | 213.6 | 213.5 |
| 22 | 52.5 | 34.7 | 76.5 | 53.9 | 52.6 | 52.5 | 35.0 | 52.5 | 76.5 | 76.4 |
| 23 | 22.1 | 24.2 | 22.2 | 10.8 | 13.2 | 22.1 | 24.6 | 22.3 | 22.2 | 24.6 |
| 24 | ||||||||||
| 25 | 35.7 | 39.3 | 35.8 | 32.8 | 38.7 | 35.6 | 39.2 | 35.6 | 35.6 | 40.1 |
| 26 | 22.3 | 22.4 | 22.4 | 18.6 | 20.8 | 22.3 | 22.3 | 22.3 | 22.4 | 22.3 |
| 27 | 20.1 | 18.2 | 20.9 | 16.1 | 19.7 | 15.0 | 18.2 | 20.0 | 20.9 | 20.4 |
| 28 | 32.5 | 31.5 | 25.0 | 22.7 | 32.6 | 32.5 | 31.6 | 32.6 | 25.0 | 25.0 |
| 29 | 178.8 | 179.1 | ||||||||
| 30 | 15.1 | 32.7 | 14.7 | 15.1 | 15.1 | 20.0 | 32.9 | 15.1 | 14.8 | 14.8 |
| OCH3 | 51.6 | 51.6 | ||||||||
| 1′ | 110.5 | 110.7 | 110.6 | 92.9 | 92.8 | 108.1 | 110.6 | 111.4 | 111.3 | 110.6 |
| 2′ | 144.4 | 144.3 | 144.4 | 38.4 | 38.8 | 141.6 | 145.2 | 144.6 | 144.6 | 145.1 |
| 3′ | 138.3 | 138.5 | 138.3 | 128.2 | 128.1 | 137.6 | 137.5 | 137.6 | 137.6 | 137.5 |
| 4′ | 129.3 | 128.3 | 129.3 | 140.6 | 140.7 | 122.5 | 128.3 | 127.6 | 127.7 | 128.4 |
| 5′ | 123.3 | 123.9 | 123.4 | 96.8 | 96.8 | 125.0 | 123.8 | 124.5 | 124.5 | 123.9 |
| 6′ | 187.2 | 187.6 | 187.2 | 38.2 | 38.4 | 124.0 | 187.4 | 187.9 | 187.8 | 187.3 |
| 7′ | 126.3 | 126.1 | 126.2 | 43.6 | 43.3 | 129.2 | 126.1 | 126.1 | 126.2 | 126.1 |
| 8′ | 171.0 | 170.4 | 171.1 | 35.7 | 35.4 | 45.5 | 171.2 | 171.7 | 171.6 | 171.7 |
| 9′ | 40.1 | 39.7 | 40.8 | 32.7 | 33.0 | 38.2 | 40.0 | 40.0 | 39.9 | 40.0 |
| 10′ | 151.8 | 151.0 | 151.8 | 42.2 | 39.3 | 143.8 | 151.1 | 150.5 | 150.5 | 151.2 |
| 11′ | 34.3 | 34.3 | 34.3 | 151.2 | 150.9 | 36.6 | 34.0 | 34.2 | 34.2 | 34.0 |
| 12′ | 30.0 | 30.2 | 29.8 1 | 108.6 | 108.8 | 36.4 | 29.8 | 29.9 1 | 29.91 | 29.9 |
| 13′ | 39.0 | 40.2 | 39.0 | 19.9 | 20.0 | 37.5 | 39.0 | 39.0 | 39.0 | 39.0 |
| 14′ | 44.7 | 44.31 | 44.9 | 19.0 | 19.1 | 38.2 | 44.7 | 44.7 | 44.9 | 44.7 |
| 15′ | 28.6 | 28.4 | 28.6 | 12.5 | 12.4 | 28.3 | 28.5 | 28.5 | 28.5 | 28.5 |
| 16′ | 36.4 | 35.5 | 36.4 | 35.4 | 36.4 | 36.4 | 36.4 | 36.4 | ||
| 17′ | 30.5 | 38.2 | 30.5 | 30.4 | 30.5 | 30.5 | 30.5 | 30.5 | ||
| 18′ | 44.3 | 43.5 | 44.3 | 44.4 | 44.2 | 44.3 | 44.3 | 44.2 | ||
| 19′ | 31.1 | 32.0 | 31.1 | 29.8 | 30.8 | 30.9 | 30.8 | 30.9 | ||
| 20′ | 40.6 | 41.9 | 40.7 | 40.6 | 40.4 | 40.4 | 40.4 | 40.5 | ||
| 21′ | 29.7 1 | 214.7 | 29.7 2 | 29.8 | 29.5 | 29.9 1 | 29.8 | 29.7 | ||
| 22′ | 35.0 | 52.6 | 35.0 | 35.8 | 34.7 | 34.7 | 34.8 | 35.0 | ||
| 23′ | 13.3 | 12.8 | 13.3 | 10.8 | 13.2 | 13.0 | 13.0 | 13.2 | ||
| 24′ | ||||||||||
| 25′ | 37.6 | 38.9 | 37.7 | 22.3 | 37.7 | 37.6 | 37.6 | 37.7 | ||
| 26′ | 20.9 | 20.8 | 20.8 | 17.5 | 20.9 | 20.8 | 20.8 | 20.9 | ||
| 27′ | 18.5 | 19.7 | 18.6 | 17.0 | 18.4 | 18.3 | 18.3 | 18.5 | ||
| 28′ | 31.6 | 32.6 | 31.6 | 31.8 | 31.5 | 31.6 | 31.6 | 31.6 | ||
| 29′ | 179.3 | 179.4 | 179.3 | 178.8 | 178.7 | 178.8 | 179.1 | |||
| 30′ | 32.9 | 15.1 | 33.0 | 31.8 | 32.7 | 32.7 | 32.7 | 32.9 | ||
| OCH3 | 51.6 | 51.8 | 51.5 | 51.4 | 51.6 | 51.6 | 51.4 | |||
| Ref | [136] | [136] | [137] | [128] | [128] | [128] | [140] | [136] | [137] | [137] |
| C | D44 | D45 | D46 | D47 | D48 | D49 | D50 | |||
| 1 | 115.2 | 114.6 | 115.5 | 115.5 | 108.2 | 108.2 | 128.3 | |||
| 2 | 190.2 | 189.4 | 190.2 | 189.5 | 144.5 | 144.5 | 183.6 | |||
| 3 | 92.0 | 91.1 | 92.0 | 92.0 | 140.7 | 140.7 | 96.9 | |||
| 4 | 79.4 | 77.2 | 79.4 | 79.4 | 122.8 | 122.9 | 92.3 | |||
| 5 | 129.8 | 131.8 | 130.3 | 130.2 | 124.7 | 124.7 | 39.5 | |||
| 6 | 126.8 | 128.9 | 126.6 | 126.5 | 71.4 | 71.4 | 28.1 | |||
| 7 | 116.1 | 117.2 | 116.2 | 116.3 | 74.1 | 74.1 | 32.8 | |||
| 8 | 161.5 | 164.4 | 160.4 | 160.5 | 43.6 | 43.6 | 30.4 | |||
| 9 | 42.0 | 44.0 | 41.7 | 41.8 | 40.4 1 | 40.4 1 | 43.7 | |||
| 10 | 174.3 | 173.2 | 173.7 | 173.6 | 143.7 | 143.7 | 140.7 | |||
| 11 | 32.9 | 32.8 | 33.2 | 32.8 | 34.5 | 34.5 | 35.4 | |||
| 12 | 29.5 | 29.61 | 29.8 | 29.5 | 30.2 | 30.2 | 30.6 | |||
| 13 | 38.1 | 38.6 | 39.4 | 38.5 | 40.6 1 | 40.6 1 | 44.5 | |||
| 14 | 44.7 | 44.4 | 44.3 | 44.2 | 40.4 1 | 40.4 1 | 40.5 | |||
| 15 | 28.4 | 28.6 | 28.3 | 28.4 | 29.3 | 29.3 | 30.0 | |||
| 16 | 36.3 | 36.4 | 35.4 | 35.5 | 35.5 | 35.5 | 36.4 | |||
| 17 | 30.5 | 30.5 | 38.2 | 37.1 | 37.9 | 37.9 | 40.5 | |||
| 18 | 44.1 | 44.3 | 43.4 | 43.6 | 43.8 | 43.7 | 43.7 | |||
| 19 | 30.9 | 30.8 | 32.1 | 34.2 1 | 31.9 | 31.9 | 43.7 | |||
| 20 | 40.4 | 40.4 | 41.9 | 53.6 | 42.2 | 42.2 | 151.2 | |||
| 21 | 29.8 | 30.1 2 | 213.6 | 209.4 | 214.7 | 214.6 2 | 39.0 | |||
| 22 | 34.7 | 34.7 | 52.5 | 51.9 | 53.9 | 53.9 | 38.2 | |||
| 23 | 22.2 | 24.6 | 22.3 | 22.3 | 11.3 | 11.3 | 12.6 | |||
| 24 | ||||||||||
| 25 | 34.9 | 39.1 | 35.6 | 35.2 | 29.1 | 29.1 | ||||
| 26 | 22.5 | 22.4 | 22.3 | 22.8 | 15.7 | 15.7 | 19.1 | |||
| 27 | 18.7 | 18.2 | 20.0 | 18.2 | 19.3 | 19.2 | 32.1 | |||
| 28 | 31.6 | 31.6 | 32.6 | 32.6 | 33.1 | 33.1 | 20.5 | |||
| 29 | 178.9 | 178.8 | 175.1 | 108.7 | ||||||
| 30 | 32.7 | 32.8 | 15.1 | 25.1 | 15.2 | 15.2 | 19.9 | |||
| OCH3 | 51.6 | 51.6 | 52.6 | |||||||
| 1′ | 111.4 | 110.5 | 111.4 | 111.4 | 109.7 | 109.7 | 109.2 | |||
| 2′ | 144.7 | 145.2 | 144.7 | 144.6 | 141.5 | 141.4 | 145.0 | |||
| 3′ | 137.7 | 137.6 | 137.7 | 137.6 | 140.3 | 140.3 | 142.8 | |||
| 4′ | 127.8 | 128.6 | 127.8 | 127.8 | 121.8 | 121.8 | 122.4 | |||
| 5′ | 124.5 | 123.9 | 124.5 | 124.5 | 124.3 | 124.3 | 125.7 | |||
| 6′ | 187.7 | 187.2 | 187.7 | 187.7 | 119.7 | 119.8 | 124.4 | |||
| 7′ | 126.1 | 126.2 | 126.2 | 126.1 | 138.2 | 138.1 | 128.7 | |||
| 8′ | 170.4 | 169.9 | 170.8 | 170.7 | 43.9 | 43.9 | 45.5 | |||
| 9′ | 39.7 | 39.7 | 39.8 | 39.8 | 142.8 | 143.0 | 37.3 | |||
| 10′ | 150.4 | 151.1 | 150.3 | 150.4 | 131.8 | 131.8 | 143.3 | |||
| 11′ | 34.5 | 34.3 | 34.1 | 34.3 1 | 122.7 | 122.6 | 31.2 | |||
| 12′ | 30.2 | 30.1 2 | 29.9 | 30.1 | 37.5 | 37.4 | 30.0 | |||
| 13′ | 40.1 | 40.1 | 39.2 | 40.2 | 40.1 | 40.1 | 38.9 | |||
| 14′ | 44.0 | 43.9 | 44.3 | 44.3 | 40.7 | 40.4 1 | 38.9 | |||
| 15′ | 28.2 | 28.2 | 28.6 | 28.4 | 24.0 | 23.6 | 28.1 | |||
| 16′ | 29.6 | 29.5 1 | 35.7 | 35.5 | 35.9 | 29.5 | 36.4 | |||
| 17′ | 44.9 | 44.9 | 37.1 | 38.2 | 39.2 | 45.3 | 30.4 | |||
| 18′ | 45.0 | 45.0 | 43.9 | 43.5 | 45.7 | 46.7 | 44.5 | |||
| 19′ | 32.0 | 31.9 | 34.2 | 32.0 | 32.5 | 32.1 | 30.6 | |||
| 20′ | 40.9 | 40.9 | 53.6 | 41.9 | 42.4 | 41.3 | 40.5 | |||
| 21′ | 213.7 | 213.6 | 209.4 | 213.7 | 214.9 | 214.5 2 | 30.0 | |||
| 22′ | 76.5 | 76.7 | 51.9 | 52.6 | 51.2 | 75.4 | 36.0 | |||
| 23′ | 13.0 | 13.2 | 13.0 | 13.0 | 10.7 | 10.7 | 10.8 | |||
| 24′ | ||||||||||
| 25′ | 38.7 | 38.9 | 38.2 | 38.4 | 22.4 | 22.4 | 22.1 | |||
| 26′ | 20.9 | 20.9 | 21.2 | 20.8 | 19.6 | 19.8 | 16.9 | |||
| 27′ | 20.6 | 20.7 | 17.8 | 19.7 | 20.6 | 21.4 | 17.4 | |||
| 28′ | 25.0 | 25.0 | 32.6 | 32.6 | 31.5 | 24.2 | 31.8 | |||
| 29′ | 175.0 | 179.2 | ||||||||
| 30′ | 14.8 | 14.7 | 25.1 | 15.1 | 15.4 | 15.0 | 32.1 | |||
| OCH3 | 52.5 | 51.6 | ||||||||
| Ref | [137] | [137] | [137] | [137] | [141] | [141] | [142] |
Ref: References; 1,2,3,4,5,6,7,8,9,10: Values bearing the same superscript are interchangeable; 11: Signal bearing this superscript was superimposed on solvent signals; Solvent: CDCl3; 13C-NMR data for D4, D5 and D29 were reported by Gonzalez et al. [143] but the chemical shifts were not attributed to each carbon atom.