. 2022 Jan 31;27(3):959. doi: 10.3390/molecules27030959

Table 5.

¹³C-NMR data of lupane-type pentacyclic triterpenoids isolated from Celastraceae species (2001–2021).

C	L1 ⁺	L2	L3	L4	L5	L6	L7	L8	L9	L10
1	38.4	38.7	41.8	123.6	42.1	39.6	39.6	79.5	39.8	39.3
2	23.7	27.4	34.0	165.1	34.2	34.1	34.1	42.9	34.3	34.3
3	80.9	79.0	218.3	205.3	218.8	218.0	217.7	216.1	218.2	221.4
4	37.9	38.9	47.5	45.0	47.6	47.3	47.2	47.1	47.5	50.7
5	55.4	55.2	54.6	52.9	54.8	54.9	54.9	51.2	55.1	55.3
6	18.2	18.3	19.4	18.9	19.6	19.6	19.6	19.6	19.8	19.2
7	34.3	34.3	33.9	34.5	34.3	33.5	33.6	32.9	33.7	33.6
8	40.9	40.8	42.2	42.9	42.4	40.8	40.6	41.0	41.0	40.7
9	49.9	50.0	54.5	48.9	54.9	49.3	49.8	50.6	50.0	49.5
10	37.1	37.1	38.0	40.6	38.2	36.8	36.9	45.1	37.0	36.6
11	20.9	20.8	70.1	70.6	70.5	21.4	21.5	22.9	21.6	21.7
12	27.6 *	26.5	37.2	37.3	37.4	24.8	25.1	25.1	25.0	25.2
13	37.9	37.8	36.1	37.1	37.2	37.4	37.7	37.9	37.8	37.5
14	43.1	42.9	42.2	42.8	42.6	44.1	41.9	42.9	42.8	42.8
15	27.2	27.2	26.8	27.3	27.4	36.8	26.9	27.5	27.3	27.0
16	35.3	35.3	33.6	35.3	35.4	76.9	33.1	35.5	35.9	34.0
17	43.0	43.1	47.3	43.0	43.0	48.6	80.2	42.9	42.0	47.8
18	49.0	47.1	47.8	47.5	47.6	47.6	48.3	47.9 *	48.2	48.6
19	42.8	37.4	47.4	47.7	47.7	47.5	48.0	48.2 *	60.0	47.8
20	49.0	49.7	149.5	150.2	150.2	149.9	149.6	150.7	148.4	150.3
21	25.2 *	23.6	29.4	29.7	29.8	29.8	29.4	29.8	77.9	29.7
22	40.0	40.5	28.8	39.8	39.8	37.7	38.5	40.0	49.6	29.1
23	28.0	28.0	27.2	21.4	27.5	26.6	26.6	28.0	26.8	22.1
24	16.6	15.4	20.5	28.2	20.8	21.0	21.0	19.8	21.2	65.3
25	16.1 **	16.0	16.5	19.9	16.7	16.0	16.0	11.9	16.1	17.0
26	16.0 **	15.9	16.6	17.4	16.9	15.8	15.9	15.9	16.0	15.6
27	14.4	14.3	14.4	14.4	14.4	16.1	13.8	14.4	14.6	14.7
28	18.0	17.9	60.3	18.0	18.1	11.7		18.1	19.8	60.5
29	207.0	7.3	110.1	113.5	109.9	109.8	109.6	109.5	111.5	109.8
30	14.5	205.1	18.9	19.3	19.4	19.3	19.3	19.3	19.9	19.1
COOCH₃	21.3
COOCH₃	171.0
Ref	[144]	[145]	[146]	[147]	[148]	[149]	[145]	[150]	[14]	[151]
C	L11	L12	L13	L14	L15	L16	L17 ^a	L18	L20	L21
1	39.6	39.6	125.2	39.8	40.2	39.7	34.1	42.4	39.7	53.5
2	34.1	34.1	159.2	34.0	35.7	34.3	26.6	34.3	34.2	211.4
3	218.2	218.0	205.0	218.0	216.5	218.3	75.1	218.6	217.9	82.5
4	47.3	47.4	44.6	47.3	47.7	47.5	38.1	47.6	47.4	45.6
5	54.9	55.0	53.5	54.8	55.4	55.1	49.2	54.9	55.1	54.6
6	19.6	19.6	19.0	19.0	20.4	19.8	18.5	19.5	19.7	18.5
7	33.5	33.5	33.7	33.5	34.2	33.8	34.5	34.2	33.7	34.0
8	40.9	42.7	41.8	40.9	41.5	41.0	41.1	42.1	40.8	41.3
9	49.7	49.6	44.5	49.7	49.8	50.0	50.8	54.7	49.7	50.4
10	36.8	36.9	39.5	36.8	37.7	37.0	37.7	38.2	36.9	43.9
11	21.4	21.4	21.2	21.3	22.2	21.7	20.8	70.1	21.5	21.0
12	26.8	27.6	25.2	25.2	28.2	26.8	26.1	37.6	27.6	25.1
13	37.3	37.1	37.5	37.4	38.0	38.3	35.2	37.6	37.9	37.2
14	42.7	40.8	43.0	42.8	43.5	43.0	41.4	42.3	42.8	42.8
15	27.0	26.9	27.0	27.0	28.2	27.6	28.2	28.8	27.4	27.1
16	33.8	29.1	29.1	29.1	34.5	35.6	22.9	28.9	35.4	29.3
17	47.8	48.0	47.7	47.7	37.6	43.2	54.0	59.3	43.3	47.8
18	49.3	52.3	48.6	48.6	50.4	49.0	55.5	59.3	47.7	48.7
19	43.5	36.5	47.8	47.3	52.8	43.9	92.2	47.2	47.7	47.8
20	154.4	157.0	150.3	150.0	211.5	154.9	141.4	149.1	157.2	150.2
21	29.1	32.8	29.7	29.7	27.8	31.9	34.4	29.8	32.7	29.7
22	31.7	33.9	33.9	33.9	40.4	40.0	29.3	32.9	40.0	33.8
23	26.7	26.6	21.4	26.6	27.1	26.8	29.2	20.7	26.6	29.1
24	21.1	21.1	27.8	21.0	21.3	21.2	22.8	27.4	21.1	16.4
25	16.0	15.9	19.2	15.8	16.1	16.1	16.5	16.8	15.9	17.0
26	15.8	15.8	16.5	15.9	14.8	16.0	15.7	16.7	15.8	14.8
27	14.7	14.6	14.6	14.7	16.4	14.6	13.6	14.1	14.4	15.6
28	60.2	60.2	60.6	60.5	18.3	17.9	178.6	206.0	17.8	60.5
29	107.2	133.2	109.9	109.7		106.9	112.3	110.7	133.0	109.9
30	65.0	194.9	19.0	19.6	29.3	65.2	19.3	19.0	195.0	19.1
Ref	[152]	[153]	[151]	[149]	[14]	[14]	[153]	[151]	[148]	[73]
C	L22	L23 ^b	L24	L25	L26	L28	L29	L30	L31	L32
1	34.0	35.4	33.6	53.4	38.6	38.6	26.3	38.6	53.5	38.7
2	22.9	23.7	25.9 *	211.5	24.0	27.4	23.1	27.3	211.4	26.9
3	78.2	80.3	76.4	82.9	81.0	78.9	76.0	78.8	82.9	78.9
4	36.7	37.7	37.5	45.6	38.3	38.9	36.4	38.8	45.6	38.8
5	50.3	51.6	49.9 **	54.6	55.6	55.3	52.4	55.1	54.6	55.3
6	18.0	19.2	18.4	18.5	18.4	18.3	20.9	18.2	18.5	18.2
7	34.4	35.3	34.4	33.8	34.2	34.3	33.0	34.1	33.8	34.3
8	40.9	42.2	41.0	41.2	41.2	40.6	43.1	40.7	43.9	40.8
9	50.7	51.5	50.5 **	50.4	50.5	50.4	45.7	50.2	50.4	50.4
10	37.2	38.3	37.3	44.0	37.3	37.2	39.8	37.1	41.3	37.1
11	20.8	21.9	20.8	21.1	21.1	21.0	23.6	20.8	21.0	20.8
12	27.2	28.8	25.6 *	24.8	25.4	27.3	25.8	27.2	25.0	27.4
13	39.8	39.2	38.7	37.9	37.3	36.6	38.3	36.2	37.2	38.5
14	44.0	43.9	42.6	42.9	42.9	41.8	40.3	42.5	42.8	42.5
15	28.1	28.5	29.5	29.4	27.3	26.8	27.8	26.9	27.0	29.2
16	32.1	36.4	28.8	35.4	29.3	32.8	35.6	28.8	29.1	31.7
17	54.3	44.3	59.3	42.9	48.0	80.3	43.0	47.8	47.7	59.3
18	143.8	52.0	48.0 ***	48.2	49.0	49.2	48.3	49.6	48.6	48.6
19	139.2	38.3	47.5 ***	47.29	48.0	52.2	47.9	52.0	47.7	43.2
20	207.2	158.3	149.8	150.7	150.7	212.2	150.9	213.5	48.6	154.1
21	34.8	33.4	30.0	29.8	30.0	27.5	29.9	27.6	29.7	28.9
22	35.1	40.9	33.2	29.9	34.4	38.7	40.0	33.9	33.9	32.9
23	27.7	28.3	28.2	29.2	28.2	28.0	29.6	27.9	29.3	28.0
24	21.7	22.2	22.2	16.4	16.9	15.4	24.0	15.4	16.3	15.3
25	16.5	16.5	15.9 ****	17.0	16.4	16.2	101.4	16.0	17.0	15.9
26	16.1	16.7	16.1 ****	15.6	16.2	16.0	16.2	15.9	15.6	16.1
27	15.7	15.1	14.2	14.5	15.0	13.2	14.7	14.6	14.7	14.3
28	66.0	18.3	205.6	18.0	60.8		18.0	60.5	60.5	206.3
29		134.8	110.1	109.5	109.9		109.3		109.9	107.4
30	30.7	197.3	19.0	19.3	19.3	29.9	19.3	29.4	19.1	65.0
OCH₃	21.4	21.3					54.6
C=O	170.8	173.4			167.7
1′					126.7
2′					130.1
3′					115.8
4′					159.3
5′					130.1
6′					130.1
7′					116.3
8′					144.5
Ref	[154]	[154]	[155]	[73]	[156]	[145]	[54]	[157]	[158]	[145]
C	L33 ^a	L35 ^c	L36	L37	L38	L39	L40	L41	L42	L43
1	39.3	38.4	78.7	38.4	38.4	38.6	38.6	53.5	38.7	38.7
2	28.3	23.8	4.2	23.9	23.8	27.3	27.4	211.5	27.3	27.4
3	78.0	81.3	77.6	55.4	80.6	78.9	78.9	82.9	78.9	79.0
4	39.3	38.1	NR	38.1	37.9	38.8	38.8	45.6	38.8	38.9
5	53.2	55.4	53.1	55.4	55.4	55.2	55.2	54.6	55.5	55.3
6	30.3	18.2	17.8	18.2	18.2	18.2	18.3	18.5	18.2	18.3
7	74.4	34.1	34.0	34.2	34.3	34.2	34.2	33.8	34.3	34.3
8	47.2	41.9	41.4	40.9	40.9	40.7	40.7	41.2	40.8	40.8
9	51.1	50.3	51.4	50.3	50.4	50.3	50.2	50.4	50.4	50.2
10	37.6	37.1	43.5	37.1	37.1	37.1	37.2	44.0	37.1	37.1
11	21.3	21.8	23.8	21.0	21.0	20.7	20.9	21.1	20.7	20.9
12	26.3	25.1	25.0	25.1	25.1	27.5	27.3	24.9	25.5	27.6 ^A
13	39.3	37.3	38.1	38.1	38.1	37.2	37.0	37.9	38.7	37.7
14	44.0	42.7	37.6	43.0 *	42.9	42.3	42.7	42.9	42.5	42.7
15	34.0	27.0	27.5	27.4	27.5	29.0	27.4	27.4	29.2 *	27.3
16	32.8	29.2	35.6	35.6	35.6	28.7	35.0	35.5	28.8 *	35.4
17	26.7	48.2	42.9	42.8 *	43.0	59.3	43.0	43.0	59.3	43.3
18	49.7	48.8	48.3	48.3	48.3	48.0	49.7	48.2	48.0 **	51.2 ^B
19	47.7	47.7	48.0	47.7	48.0	51.1	52.6	47.9	47.5 **	36.7 ^C
20	151.1	150.4	150.8	151.0	151.0	211.8	212.9	150.8	149.7	157.0 ^B
21	30.9	29.7	29.8	29.9	29.9	27.6	27.6	29.8	29.8	32.6 ^B
22	37.2	34.0	40.0	40.0	40.0	32.4	39.8	39.9	33.2	39.9
23	28.5	28.0	27.8	28.0	28.0	28.0	28.0	29.3	27.9	28.0
24	16.4	16.7	16.2	16.7	16.6	15.4	15.4	16.4	15.4	15.4
25	16.3	16.2	12.0	16.2 **	16.2	16.1	16.1	17.0	15.9 ***	16.1
26	10.9	16.0	16.2	16.0 **	16.0	15.8	15.9	15.6	16.1 ***	15.9
27	15.1	14.8	14.4	14.5	14.5	14.2	14.5	14.5	14.2	14.4
28	176.6	60.6	17.9	18.0	18.0	206.1	18.0	18.0	205.6	17.8
29	110.0	109.8	109.4	109.4	109.4	30.2	29.2	109.5	110.1	132.9 ^B
30	19.5	19.1	19.2	19.3	19.3			19.3	19.0	195.1
1′		127.3	167.6	127.1	173.7
2′		115.3	115.7	115.1	34.9
3′		144.2	145.1	144.9	25.2
4′		146.8	127.4	147.3	29.2
5′		114.2	114.4	113.9	29.3
6′		122.3	144.0	122.0	29.4
7′		144.9	146.6	144.9	29.6
8′		115.8	115.5	115.7	29.7
9′–14′		168.0	122.4	167.7	29.7
15′					29.5
16′					31.9
17′					22.7
18′					14.1
Ref	[153]	[159]	[160]	[159]	[161]	[145]	[145]	[162]	[155]	[163]
C	L44	L45	L46	L47	L48	L49	L50^a	L51	L52	L53
1	42.5	42.5	42.1	42.1	38.4	40.9	42.6	38.4	40.1	39.8
2	34.4	34.4	34.4	34.5	27.7	178.5	174.4	36.2	34.5	34.3
3	216.8	216.8	216.7	216.8	81.0	187.5	182.4	217.2	216.3	218.3
4	48.9	48.9	48.9	49.0	37.8	45.6	46.9	47.0	42.2	47.0
5	56.6	56.6	56.5	56.6	55.4	48.2	48.4	49.6	56.5	55.1
6	69.7	69.7	69.6	69.7	18.2	21.3	21.6	19.9	69.8	19.8
7	42.1	42.1	42.2	42.2	34.2	33.7	33.8	33.5	41.9	37.2
8	40.7	40.7	40.0	40.0	40.9	41.8	41.1	40.8	37.5	40.8
9	50.6	50.6	50.6	50.5	50.4	41.7	42.0	52.4	50.9 *	50.0
10	36.8	36.8	36.7	36.7	37.1	40.7	42.3	36.6	34.5	37.1
11	21.8	21.8	21.3	21.3	21.0	19.2	22.2	21.7	21.3	21.5
12	28.7	28.7	26.7	29.7	25.1	24.9	27.3	26.0	25.2	25.7
13	36.8	36.8	37.1	36.8	38.1	37.9	38.6	38.6	37.5	38.6
14	43.9	43.9	42.9	43.2	42.8	43.2	43.5	42.7	42.9	42.6
15	27.7	27.7	27.4	27.4	27.5	27.5	27.9	31.1	29.9	29.8
16	35.6	35.6	35.3	35.3	35.6	35.5	35.6	32.6	32.2	32.2
17	44.6	44.6	43.1	43.0	43.0	43.2	43.2	56.4	56.9	56.5
18	48.5	48.5	48.9	50.6	48.3	48.4	48.9	47.5	49.5 *	49.3
19	50.1	50.1	43.7	42.1	48.0	48.0	43.8	49.6	47.0	47.5
20	73.4	73.4	154.6	157.2	151.0	150.9	156.5	151.1	150.3	150.5
21	29.1	29.1	31.7	32.7	30.0	29.8	32.2	30.0	30.7	30.7
22	40.2	40.2	39.8	39.8	40.0	39.9	40.0	37.3	37.0	33.8
23	24.9	24.9	25.0	25.0	27.1	29.8	27.8	68.0	25.7	26.8
24	23.7	23.7	23.7	23.7	16.2	21.3	24.8	17.2	21.3	21.2
25	17.5	17.5	17.0	16.9	16.5	20.8	20.4	16.0	17.3 **	16.1
26	17.0	17.0	17.1	17.1	16.0	15.9	16.3	15.9	17.1 **	16.0
27	15.2	15.2	14.8	14.7	14.5	14.6	15.0	14.6	15.0	14.8
28	19.2	19.2	17.7	17.8	18.0	18.0	17.9	178.6	181.9	181.2
29	31.7	31.7	106.9	133.2	109.4	109.4	105.9	109.6	109.8	109.9
30	25.2	25.2	65.0	195.1	19.3	19.2	64.3	19.3	19.5	19.5
C=O					171.0
OCH₃					21.3
Ref	[164]	[164]	[146]	[146]	[165]	[73]	[153]	[166]	[167]	[14]
C	L54	L55	L56	L57 ^a	L58 ^d	L59 ^a	L61	L62	L63	L64
1	39.6	33.9	34.0	34.0	34.0	38.7	159.9	38.7	75.9	75.9
2	34.1	28.1	26.2	26.7	25.1	28.4	125.1	27.4	36.4	36.4
3	218.2	179.1	75.0	75.3	76.9	78.2	205.6	79.0	76.6	76.9
4	47.3	147.5	38.1	38.2	38.5	39.4	44.6	38.8	37.4	37.5
5	54.9	50.4	46.4	49.3	54.9	56.0	53.4	55.3	47.8	47.9
6	19.6	24.5	26.1	18.7	18.0	18.9	19.0	18.3	18.4	18.5
7	33.6	32.8	76.7	34.7	33.9	34.9	33.7	34.3	34.0	34.1
8	40.7	40.9	46.3	41.2	41.2	41.2	41.7	40.8	42.9	41.7
9	49.6	40.4	51.2	50.5	49.9	51.0	44.4	50.4	51.2	51.3
10	36.8	39.2	37.8	37.7	36.7	37.6	39.5	37.1	37.4	43.7
11	21.5	21.4	20.8	21.2	20.5	21.3	21.2	21.0	23.7	23.9
12	29.7	25.4	26.5	28.2	27.1	26.2	25.1	26.7	25.2	25.2
13	37.8	38.3	39.1	38.2	37.6	39.6	38.2	38.0	36.9	37.7
14	42.8	42.8	44.4	43.1	42.6	42.9	43.0	43.0	41.7	42.9 *
15	27.3	30.6	33.0	27.8	31.7	31.3	27.4	27.4	27.1	27.5
16	35.4	32.1	33.4	35.9	36.4	33.0	35.5	35.5	29.2	35.7
17	43.1	56.5	56.3	43.5	55.5	56.7	43.1	42.8	43.6	43.0 *
18	50.9	49.4	49.6	51.3	46.7	47.9	48.1	48.9	48.8	48.1 **
19	40.7	46.9	48.0	41.4	48.7	49.9	47.3	43.8	47.8	48.4 **
20	146.3	150.4	151.4	149.2	150.4	151.4	150.8	154.8	150.3	150.8
21	32.9	29.7	31.2	33.5	30.1	30.4	29.8	31.8	29.7	29.8
22	39.7	36.9	37.7	40.2	38.3	37.7	40.0	39.8	34.0	40.0
23	26.6	113.4	29.0	29.4	28.1	28.8	27.8	28.0	27.7	27.6
24	21.0	23.2	22.4	22.7	15.8	16.4	21.4	16.1	21.9	22.0
25	15.9	20.1	16.1	16.3	15.9	16.5	19.2	16.0	11.7	11.5
26	15.8	15.9	12.1	16.4	16.0	16.5	16.4	15.4	16.2	16.1
27	14.4	14.6	15.1	14.8	14.4	15.0	14.4	14.5	14.8	14.6
28	17.9	176.6	179.0	18.2	177.3	178.9	18.0	17.7	60.6	18.1
29	124.9	109.7	109.9	122.4	109.6	110.0	109.5	107.6	109.8	109.5
30	171.2	19.3	19.5	170.3	19.0	19.6	19.3	65.0	19.0	19.3
OCH₃		51.3			51.3
1′			166.3
2′			117.6
3′			156.4
4′			27.0
5′			20.2
Ref	[146]	[118]	[153]	[154]	[168]	[169]	[170]	[145]	[146]	[150]
C	L65	L66	L67	L68	L69	L70	L71	L72	L73	L74
1	79.0	44.5	39.5	39.6	35.5	35.4	33.5	32.5	39.0	38.9
2	37.5	71.3	34.1	34.2	25.6	25.6	28.2	25.3	27.5	27.4
3	75.7	78.5	217.8	218.1	75.9	75.9	76.0	76.4	78.6	78.9
4	38.9	38.2	47.3	47.3	37.8	37.8	38.8	37.6	39.4	38.8
5	53.1	55.2	54.9	54.9	48.9	48.9	48.5	48.2	55.6	54.9
6	18.0	18.1	19.6	19.7	18.0	18.3	21.1	18.4	18.1	18.5
7	34.1	34.2	33.2	33.6	35.1	35.1	34.2	34.4	35.3	37.8
8	41.3	40.9	40.9	40.8	42.6	42.7	40.9	41.1	41.1	42.5
9	51.4	50.9	49.6	49.8	55.6	55.6	50.4	50.5	55.7	51.0
10	43.5	36.9	36.8	36.9	39.1	39.1	37.3	37.3	37.7	37.4
11	23.8	21.1	21.2	21.5	70.5	70.6	20.8	21.2	70.5	21.0
12	25.0	25.2	25.3	25.2	37.6	37.6	25.2	25.3	27.7	25.2
13	38.0	38.0	37.3	38.2	36.3	37.1	37.1	38.0	37.7	37.6
14	42.8	42.9	42.7	42.9	42.9	42.7	42.7	43.0	42.6	47.9
15	27.4	27.3	26.9	27.4	27.0	27.3	27.1	27.6	27.5	69.7
16	35.5	35.6	34.8	35.5	33.8	35.4	29.2	35.8	35.5	46.5
17	42.9	43.0	37.8	43.0	47.8	43.0	48.1	43.2	43.0	43.0
18	48.3	48.3	47.0	48.3	48.2	47.7	47.8	48.2	47.7	48.1
19	47.9	48.0	59.0	48.0	47.6	47.7	48.0	48.2	47.4	47.4
20	150.8	151.0	143.4	150.6	149.8	150.2	150.4	151.2	150.2	150.4
21	29.7	29.9	217.7	29.9	29.1	29.8	29.8	29.9	29.9	30.1
22	39.9	40.0	55.4	40.0	29.3	39.8	34.0	40.2	39.9	39.7
23	27.8	29.6	26.6	26.7	22.3	22.3	28.1	28.2	28.3	27.9
24	14.9	17.1	21.0	21.0	28.7	28.7	16.0	22.4	15.6	15.4
25	11.9	17.1	15.9	16.0	16.3	16.2	16.1	16.4	16.1	16.1
26	16.2	16.0	15.7	15.8	17.2	17.2	16.1	16.2	17.3	16.6
27	14.4	14.5	14.5	14.5	14.1	14.6	14.8	14.7	14.5	8.0
28	18.0	18.0	18.7	18.0	60.2	18.0	60.1	18.2	18.1	19.2
29	109.4	109.3	115.0	109.4	110.2	109.8	109.6	109.6	109.8	109.7
30	19.2	19.3	20.8	19.3	19.1	19.3	18.9	19.5	19.4	19.4
Ref	[171]	[172]	[40]	[145]	[151]	[147]	[173]	[174]	[175]	[176]
C	L75	L76 ^c	L77	L78^c	L79	L80	L81	L82	L83	L84
1	38.7	38.7	34.2	38.2	38.7	38.9	40.7	38.7	38.4	40.7
2	27.3	27.5	27.2	30.6	27.0	27.5	29.7	27.4	27.0	27.6
3	78.3	78.9	79.0	82.3	79.0	78.8	79.1	78.8	76.8	79.1
4	38.8	38.7	38.9	40.9	38.9	38.8	39.6	38.3	41.9	39.6
5	55.6	55.2	55.4	59.5	55.3	55.4	55.6	55.2	49.9	55.5
6	18.2	18.3	18.2	22.0	18.3	18.3	69.0	18.3	18.4	69.1
7	34.1	34.5	34.1	37.5	34.2	33.4	42.1	34.2	34.0	42.4
8	40.8	41.3	40.8	42.7	40.9	40.9	39.9	40.9	40.8	40.4
9	49.4	50.2	50.4	54.5	50.4	50.4	51.9	50.3	50.4	50.9
10	36.8	37.0	42.6	32.2	37.1	37.2	36.7	37.1	37.0	36.6
11	21.4	21.4	20.8	24.7	20.8	21.0	21.1	20.9	21.4	21.6
12	24.8	27.4	25.3	30.8	25.1	26.7	25.3	25.1	26.6	28.8
13	37.4	37.4	37.9	41.3	37.3	38.0	37.2	38.0	37.9	36.6
14	44.1	44.6	42.9	44.8	42.7	42.8	43.0	42.8	42.8	43.8
15	36.8	27.7	27.2	33.0	27.3	27.5	27.5	27.4	27.4	27.5
16	76.9	35.5	35.3	38.0	29.2	35.5	35.5	35.5	35.4	35.5
17	48.6	43.5	42.8	46.4	47.8	43.0	43.1	42.9	43.0	44.6
18	47.6	48.3	48.2	53.3	48.7	48.9	48.4	48.2	48.8	48.4
19	47.4	49.9	47.8	47.4	47.8	43.8	48.0	47.9	43.8	49.9
20	150.0	73.5	150.4	150.7	150.5	155.2	150.9	150.6	154.7	73.5
21	29.8	29.0	29.7	35.4	29.8	31.8	29.9	29.8	31.7	29.2
22	37.7	40.2	40.0	33.1	33.9	39.9	40.0	39.9	39.8	40.2
23	28.0	28.0	28.0	31.2	27.9	28.1	27.6	28.0	72.1	27.7
24	15.0	15.4	15.6	19.3	15.3	15.4	16.6	15.4	11.2	16.9
25	16.0	16.1	60.7	18.6	16.1	16.0	17.7	16.1	16.5	17.8
26	16.0	16.1	16.2	19.2	15.9	16.1	16.9	15.9	16.0	17.2
27	16.0	14.8	14.8	17.8	14.7	14.6	14.9	14.5	14.6	15.2
28	11.6	19.2	18.1	62.9	60.6	17.7	18.0	18.0	17.7	19.2
29	109.6	24.7	109.9	109.8	109.7	106.4	109.4	109.2	106.8	24.8
30	19.0	31.5	19.2	67.8	19.0	64.6	19.3	19.3	65.0	31.6
Ref	[149]	[177]	[178]	[157]	[179]	[148]	[151]	[180]	[145]	[146]
C	L85	L86
1	40.7	39.5
2	27.5	34.0
3	79.1	217.8
4	39.6	47.2
5	55.6	54.7
6	68.9	19.6
7	42.0	33.4
8	40.0	40.8
9	51.0	49.2
10	36.7	36.8
11	21.0	21.2
12	25.3	26.5
13	36.4	37.7
14	42.9	43.0
15	27.1	27.7
16	33.6	34.5
17	47.7	43.8
18	48.8	52.2
19	47.7	45.0
20	150.4	139.1
21	29.7	82.2
22	29.1	47.7
23	27.6	26.7
24	16.9	21.0
25	17.7	15.9
26	16.9	15.7
27	15.1	14.1
28	60.4	19.3
29	109.7	124.7
30	19.1	171.2
Ref	[151]	[181]

Ref: References; ^{+ 13}C-NMR data of acetylated compound, *, **, ***, **** Values bearing the same superscript are interchangeable; NR: Not reported; Solvent: CDCl₃; ^a Pyridine-d₅; ^b CD₃COOD; ^c CD₃OD; ^d DMSO-d₆; ^A Slightly broadened peak, measured at 25 °C; ^B Broad peak, measured at 35°C; ^C Very broad peak, determined from HSQC and HMBC spectra at 35°. ¹³C-NMR data for L19, L27 [159], L34, L60, L87 [182,183], L88 [182,183] and L89 were not found. These compounds were identified on the references cited here by comparison of spectroscopic data with those reported in the literature, but we could not get access to the original papers.