Table 7.
13C-NMR data of ursane-type pentacyclic triterpenoids isolated from Celastraceae species (2001–2021).
| C | U1 | U2 | U3 a | U4 | U5 | U6 | U7 | U8 | U9 | U10 |
|---|---|---|---|---|---|---|---|---|---|---|
| 1 | 41.4 | 41.1 | 42.5 | 40.8 | 40.8 | 41.4 | 39.2 | 39.0 | 39.0 | 47.2 |
| 2 | 34.2 | 34.5 | 35.1 | 27.4 | 27.7 | 34.3 | 34.5 | 28.3 | 28.3 | 69.1 |
| 3 | 217.6 | 220.9 | 217.2 | 78.4 | 78.6 | 217.6 | 220.2 | 76.9 | 77.0 | 85.0 |
| 4 | 47.6 | 51.1 | 48.3 | 39.0 | 39.1 | 47.7 | 51.3 | 52.9 | 52.9 | 43.4 |
| 5 | 55.0 | 55.5 | 56.1 | 54.8 | 54.9 | 55.6 | 55.9 | 56.3 | 56.4 | 56.1 |
| 6 | 19.9 | 19.3 | 20.5 | 18.4 | 18.4 | 19.7 | 19.4 | 18.5 | 18.5 | 18.3 |
| 7 | 36.4 | 36.6 | 34.4 | 37.2 | 37.8 | 33.3 | 36.8 | 37.5 | 37.6 | 34.4 |
| 8 | 43.7 | 43.6 | 43.5 | 43.7 | 43.8 | 37.6 | 43.8 | 43.9 | 43.9 | 42.9 |
| 9 | 52.8 | 52.4 | 53.8 | 51.6 | 50.5 | 54.4 | 44.9 | 45.3 | 45.1 | 46.4 |
| 10 | 37.7 | 37.3 | 38.5 | 38.4 | 38.3 | 43.1 | 37.6 | 38.5 | 38.5 | 39.2 |
| 11 | 69.5 | 70.0 | 70.2 | 68.0 | 75.1 | 68.7 | 76.5 | 76.5 | 76.6 | 76.7 |
| 12 | 146.3 | 145.5 | 148.4 | 146.2 | 145.0 | 129.0 | 142.9 | 143.7 | 143.9 | 141.9 |
| 13 | 115.1 | 116.3 | 113.2 | 116.5 | 123.1 | 142.8 | 119.1 | 118.0 | 119.1 | 118.3 |
| 14 | 46.8 | 46.9 | 44.2 | 46.6 | 47.2 | 42.5 | 46.6 | 46.5 | 46.5 | 40.6 |
| 15 | 68.0 | 68.1 | 37.8 | 68.2 | 68.1 | 28.0 | 68.0 | 67.9 | 68.0 | 27.1 |
| 16 | 38.1 | 38.9 | 65.9 | 38.7 | 38.8 | 26.6 | 39.0 | 38.2 | 38.9 | 27.5 |
| 17 | 33.7 | 34.2 | 39.5 | 34.1 | 34.1 | 33.8 | 34.2 | 33.7 | 34.2 | 33.3 |
| 18 | 42.0 | 47.5 | 49.9 | 46.1 | 46.7 | 58.5 | 47.5 | 42.2 | 47.5 | 47.7 |
| 19 | 41.2 | 40.5 | 41.9 | 40.3 | 38.9 | 39.4 | 40.5 | 41.3 | 40.5 | 40.8 |
| 20 | 71.6 | 39.3 | 40.7 | 39.6 | 39.5 | 39.5 | 39.3 | 71.4 | 39.3 | 39.5 |
| 21 | 35.6 | 31.0 | 31.8 | 31.0 | 31.0 | 31.1 | 31.1 | 35.5 | 31.0 | 31.2 |
| 22 | 35.7 | 41.0 | 36.8 | 41.1 | 41.1 | 41.3 | 41.1 | 35.9 | 41.2 | 41.6 |
| 23 | 26.8 | 22.4 | 27.5 | 28.3 | 28.4 | 26.9 | 22.5 | 19.4 | 19.4 | 23.2 |
| 24 | 21.4 | 65.9 | 22.1 | 15.8 | 15.8 | 21.2 | 65.9 | 207.8 | 207.7 | 65.6 |
| 25 | 16.3 | 17.3 | 16.9 | 16.7 | 16.4 | 16.2 | 16.6 | 15.5 | 15.4 | 18.1 |
| 26 | 18.5 | 18.3 | 18.9 | 18.7 | 19.2 | 17.5 | 18.3 | 18.7 | 18.7 | 18.1 |
| 27 | 17.6 | 17.6 | 26.0 | 18.0 | 17.6 | 23.0 | 17.3 | 17.5 | 17.5 | 23.9 |
| 28 | 29.0 | 29.3 | 23.6 | 29.3 | 29.2 | 28.7 | 29.1 | 28.8 | 29.0 | 28.5 |
| 29 | 11.5 | 16.8 | 17.8 | 17.6 | 18.3 | 18.0 | 17.0 | 12.0 | 17.0 | 17.0 |
| 30 | 29.8 | 21.0 | 22.0 | 21.0 | 21.1 | 21.5 | 21.1 | 29.9 | 21.1 | 21.2 |
| Ref | [193] | [193] | [190] | [54] | [54] | [228] | [193] | [193] | [193] | [193] |
| C | U11 | U12 | U13 | U14 | U15 | U16 | U17 | U18 a | U19 | U20 |
| 1 | 40.8 | 39.0 | 38.7 | 39.0 | 38.7 | 39.0 | 39.9 | 40.6 | 39.9 | 40.3 |
| 2 | 34.4 | 27.5 | 27.8 | 27.5 | 27.9 | 27.5 | 27.5 | 28.5 | 26.9 | 34.2 |
| 3 | 218.3 | 78.6 | 80.4 | 78.6 | 80.5 | 78.7 | 78.7 | 77.9 | 78.9 | 217.9 |
| 4 | 47.6 | 39.1 | 43.1 | 39.1 | 43.1 | 39.2 | 30.9 | 38.5 | 39.1 | 47.6 |
| 5 | 55.3 | 55.1 | 55.7 | 55.1 | 56.1 | 55.5 | 54.9 | 55.8 | 55.3 | 55.2 |
| 6 | 19.7 | 18.4 | 18.5 | 18.4 | 18.3 | 18.2 | 18.6 | 18.8 | 18.4 | 19.6 |
| 7 | 33.2 | 37.3 | 37.6 | 37.4 | 34.4 | 34.2 | 36.5 | 33.6 | 33.5 | 33.0 |
| 8 | 42.7 | 44.2 | 44.1 | 44.2 | 40.6 | 40.6 | 44.2 | 43.2 | 42.9 | 43.2 |
| 9 | 50.9 | 46.9 | 46.3 | 46.3 | 46.5 | 46.4 | 52.7 | 53.1 | 52.6 | 47.2 |
| 10 | 37.6 | 38.4 | 38.1 | 38.5 | 38.1 | 38.4 | 38.1 | 39.7 | 38.2 | 37.3 |
| 11 | 77.0 | 76.4 | 76.6 | 76.4 | 76.8 | 76.7 | 76.5 | 76.7 | 76.8 | 81.7 |
| 12 | 124.2 | 144.0 | 143.0 | 143.1 | 142.1 | 142.1 | 125.2 | 124.9 | 124.1 | 125.4 |
| 13 | 143.3 | 117.9 | 119.1 | 119.2 | 118.2 | 118.2 | 144.1 | 143.1 | 143.6 | 144.2 |
| 14 | 42.4 | 46.4 | 46.4 | 46.4 | 42.9 | 42.9 | 47.7 | 42.2 | 41.5 | 44.2 |
| 15 | 26.6 | 68.0 | 68.1 | 68.1 | 27.1 | 27.2 | 68.2 | 26.7 | 27.6 | 35.8 |
| 16 | 27.9 | 38.0 | 38.8 | 38.7 | 27.6 | 27.6 | 38.8 | 23.7 | 28.1 | 66.7 |
| 17 | 33.8 | 33.6 | 34.1 | 34.1 | 33.3 | 33.3 | 33.9 | 38.6 | 33.7 | 38.5 |
| 18 | 58.8 | 42.2 | 47.5 | 47.5 | 47.7 | 47.7 | 58.7 | 53.8 | 58.6 | 60.3 |
| 19 | 39.3 | 41.3 | 40.5 | 40.5 | 40.8 | 40.8 | 39.3 | 39.8 | 39.4 | 39.4 |
| 20 | 39.5 | 71.5 | 39.3 | 39.3 | 39.5 | 39.5 | 39.1 | 39.4 | 39.6 | 39.2 |
| 21 | 31.1 | 35.5 | 31.0 | 31.0 | 31.2 | 31.3 | 30.9 | 31.1 | 31.2 | 30.4 |
| 22 | 41.3 | 35.9 | 41.2 | 41.2 | 41.6 | 41.6 | 41.0 | 36.1 | 42.1 | 35.0 |
| 23 | 26.9 | 28.3 | 22.7 | 28.4 | 22.7 | 28.4 | 28.2 | 28.8 | 28.3 | 26.0 |
| 24 | 21.4 | 15.8 | 64.4 | 15.8 | 64.5 | 15.8 | 15.6 | 16.6 | 15.7 | 21.4 |
| 25 | 16.6 | 16.3 | 16.8 | 16.2 | 16.8 | 16.2 | 17.1 | 17.4 | 17.1 | 18.0 |
| 26 | 18.2 | 18.7 | 18.6 | 18.7 | 18.0 | 18.1 | 18.9 | 18.3 | 18.3 | 16.2 |
| 27 | 22.5 | 17.7 | 17.8 | 17.8 | 23.8 | 23.9 | 16.6 | 22.7 | 22.6 | 23.2 |
| 28 | 28.7 | 28.7 | 29.0 | 29.0 | 28.5 | 28.5 | 29.3 | 69.1 | 28.8 | 21.9 |
| 29 | 17.5 | 11.9 | 17.0 | 17.0 | 17.0 | 17.0 | 17.3 | 17.6 | 17.5 | 17.7 |
| 30 | 21.3 | 29.9 | 21.2 | 21.2 | 21.2 | 21.2 | 21.3 | 21.6 | 21.5 | 21.2 |
| OCH3 | 54.4 | 52.0 | 51.6 | 51.5 | 51.6 | 51.4 | 54.7 | 53.9 | ||
| Ref | [104] | [193] | [193] | [54] | [193] | [54] | [54] | [189] | [74] | [229] |
| C | U21 | U22 | U23 | U24 | U25 | U26 b | U27 | U28 | U29 a | U31 |
| 1 | 40.1 | 39.3 | 39.9 | 39.4 | 39.4 | 40.2 | 38.3 | 39.5 | 38.6 | 39.2 |
| 2 | 34.2 | 34.3 | 34.1 | 34.3 | 34.4 | 26.6 | 27.1 | 27.7 | 27.6 | 33.9 |
| 3 | 218.0 | 219.3 | 216.7 | 219.1 | 219.4 | 83.1 | 78.9 | 79.6 | 73.1 | 217.1 |
| 4 | 47.6 | 51.44 | 47.7 | 51.5 | 51.5 | 44.3 | 38.8 | 40.0 | 43.1 | 47.5 |
| 5 | 55.3 | 55.6 | 55.1 | 55.7 | 55.7 | 48.4 | 54.5 | 56.2 | 48.2 | 54.4 |
| 6 | 19.7 | 18.7 | 19.0 | 18.8 | 18.7 | 18.8 | 17.9 | 18.8 | 18.0 | 19.1 |
| 7 | 32.4 | 35.6 | 35.5 | 35.7 | 35.6 | 34.6 | 35.1 | 32.7 | 31.6 | 34.4 |
| 8 | 43.0 | 46.2 | 46.6 | 46.3 | 46.3 | 44.2 | 43.0 | 43.1 | 42.1 | 42.9 |
| 9 | 47.8 | 58.7 | 59.1 | 58.7 | 58.7 | 49.6 | 52.7 | 53.7 | 53.5 | 52.1 |
| 10 | 37.4 | 36.5 | 36.9 | 36.6 | 36.5 | 39.1 | 36.5 | 37.5 | 36.6 | 36.2 |
| 11 | 81.8 | 194.2 | 194.4 | 194.2 | 194.2 | 78.4 | 129.4 | 132.9 | 133.8 | 129.0 |
| 12 | 124.8 | 145.1 | 145.1 | 145.1 | 145.0 | 145.8 | 132.5 | 131.5 | 129.3 | 132.8 |
| 13 | 146.1 | 132.9 | 133.9 | 133.9 | 134.7 | 116.9 | 85.8 | 85.8 | 84.9 | 85.6 |
| 14 | 42.0 | 47.3 | 47.4 | 47.4 | 47.4 | 44.3 | 48.9 | 46.9 | 44.6 | 49.1 |
| 15 | 27.9 | 68.1 | 68.3 | 68.3 | 68.3 | 36.4 | 68.4 | 36.0 | 25.8 | 68.3 |
| 16 | 26.3 | 38.4 | 38.0 | 38.6 | 38.6 | 78.3 | 37.8 | 66.4 | 27.3 | 37.2 |
| 17 | 33.8 | 33.9 | 33.7 | 34.1 | 34.2 | 39.7 | 42.7 | 48.4 | 42.5 | 42.3 |
| 18 | 58.7 | 47.5 | 43.6 | 48.6 | 48.7 | 50.9 | 61.0 | 63.3 | 61.6 | 55.3 |
| 19 | 39.4 | 35.5 | 41.4 | 34.8 | 40.6 | 42.1 | 37.6 | 39.3 | 37.9 | 38.8 |
| 20 | 39.3 | 51.4 | 70.9 | 46.4 | 39.1 | 41.0 | 40.6 | 42.1 | 41.0 | 71.7 |
| 21 | 31.1 | 25.3 | 35.4 | 24.9 | 30.9 | 32.5 | 31.2 | 30.5 | 31.7 | 35.9 |
| 22 | 41.3 | 39.7 | 35.6 | 40.4 | 40.7 | 36.7 | 34.0 | 31.8 | 35.2 | 29.0 |
| 23 | 26.5 | 22.1 | 26.4 | 22.1 | 22.0 | 67.4 | 27.7 | 28.4 | 67.4 | 26.0 |
| 24 | 21.4 | 65.6 | 21.4 | 65.6 | 65.6 | 13.6 | 14.9 | 15.7 | 12.5 | 20.8 |
| 25 | 18.1 | 16.7 | 15.8 | 16.6 | 16.7 | 17.6 | 17.7 | 18.4 | 18.5 | 17.1 |
| 26 | 16.2 | 18.5 | 18.9 | 18.6 | 18.6 | 18.9 | 19.9 | 20.1 | 19.8 | 19.6 |
| 27 | 22.0 | 15.4 | 15.1 | 15.1 | 15.1 | 25.2 | 12.8 | 19.0 | 17.4 | 12.5 |
| 28 | 28.5 | 29.1 | 29.2 | 29.3 | 29.5 | 23.7 | 76.8 | 73.1 | 76.8 | 76.5 |
| 29 | 17.5 | 17.4 | 11.6 | 16.2 | 16.6 | 17.6 | 18.1 | 18.9 | 18.4 | 12.9 |
| 30 | 21.3 | 176.4 | 29.7 | 65.7 | 20.9 | 21.7 | 19.4 | 19.8 | 19.5 | 28.7 |
| OCH3 | 53.5 | |||||||||
| 1′ | 105.8 | |||||||||
| 2′ | 75.7 | |||||||||
| 3′ | 78.4 | |||||||||
| 4′ | 71.8 | |||||||||
| 5′ | 77.6 | |||||||||
| 6′ | 62.8 | |||||||||
| 1″ | 106.1 | |||||||||
| 2″ | 75.7 | |||||||||
| 3″ | 78.3 | |||||||||
| 4″ | 71.6 | |||||||||
| 5″ | 77.8 | |||||||||
| 6″ | 62.9 | |||||||||
| Ref | [229] | [193] | [54] | [193] | [54] | [230] | [54] | [189] | [189] | [193] |
| C | U32 | U33 | U34 a | U35 | U36 a | U37 a | U38 | U39 | U40 | U41 |
| 1 | 40.9 | 40.9 | 39.5 | 47.1 | 48.0 | 47.9 | 38.6 | 39.8 | 39.8 | 33.5 |
| 2 | 28.2 | 27.4 | 34.2 | 68.6 | 68.7 | 68.8 | 23.8 | 25.9 | 34.2 | 25.3 |
| 3 | 76.9 | 78.7 | 217.8 | 84.9 | 85.7 | 85.8 | 81.1 | NR | 217.1 | 75.8 |
| 4 | 52.8 | 39.0 | 47.4 | 43.4 | 43.9 | 43.9 | 38.1 | 38.7 | 47.8 | 37.5 |
| 5 | 55.8 | 54.7 | 55.2 | 55.5 | 56.5 | 56.6 | 55.4 | 56.7 | 55.4 | 48.3 |
| 6 | 18.6 | 18.5 | 19.6 | 17.6 | 19.1 | 19.3 | 18.3 | 18.8 | 18.8 | 17.4 |
| 7 | 35.6 | 35.0 | 32.3 | 33.1 | 33.8 | 33.9 | 32.9 | 34.3 | 32.2 | 32.7 |
| 8 | 43.8 | 44.7 | 40.0 | 45.5 | 40.2 | 40.7 | 40.2 | 41.3 | 43.7 | 45.3 |
| 9 | 52.7 | 55.7 | 46.8 | 59.5 | 48.2 | 48.0 | 47.7 | 49.4 | 60.8 | 61.4 |
| 10 | 38.3 | 38.2 | 36.6 | 37.4 | 38.2 | 38.3 | 36.9 | 38.0 | 36.6 | 37.0 |
| 11 | 70.0 | 67.8 | 23.3 | 194.8 | 24.0 | 24.4 | 23.5 | 24.2 | 199.0 | 200.0 |
| 12 | 146.1 | 130.2 | 125.3 | 144.4 | 125.7 | 128.1 | 125.1 | 125.1 | 130.6 | 130.7 |
| 13 | 116.1 | 142.7 | 138.4 | 134.8 | 138.7 | 139.5 | 138.9 | 140.8 | 164.8 | 164.3 |
| 14 | 45.9 | 47.0 | 42.2 | 41.7 | 42.4 | 42.1 | 42.2 | 43.3 | 45.5 | 43.7 |
| 15 | 72.2 | 72.1 | 25.9 | 27.5 | 29.3 | 29.9 | 26.1 | 26.7 | 27.2 | 27.1 |
| 16 | 34.2 | 34.5 | 23.3 | 27.3 | 24.4 | 25.9 | 23.7 | 24.1 | 27.4 | 27.5 |
| 17 | 34.0 | 33.9 | 37.9 | 33.4 | 48.3 | 48.6 | 38.1 | 37.7 | 33.8 | 33.8 |
| 18 | 47.4 | 58.3 | 54.0 | 48.9 | 53.3 | 54.5 | 54.2 | 55.3 | 58.8 | 58.8 |
| 19 | 40.6 | 39.1 | 33.7 | 40.8 | 39.4 | 72.7 | 39.5 | 41.4 | 33.5 | 33.5 |
| 20 | 39.3 | 39.2 | 46.7 | 39.3 | 39.2 | 42.2 | 39.5 | 40.7 | 46.5 | 46.5 |
| 21 | 30.9 | 30.8 | 24.5 | 31.1 | 30.8 | 26.8 | 30.7 | 32.2 | 24.8 | 24.6 |
| 22 | 40.7 | 40.7 | 34.7 | 41.1 | 36.4 | 37.5 | 35.3 | 36.5 | 40.5 | 40.5 |
| 23 | 18.7 | 28.2 | 26.4 | 23.0 | 24.2 | 24.2 | 28.2 | 28.3 | 28.8 | 28.4 |
| 24 | 207.6 | 15.6 | 21.5 | 65.3 | 65.7 | 65.7 | 17.0 | 17.5 | 22.1 | 22.3 |
| 25 | 15.7 | 16.8 | 15.5 | 18.3 | 17.5 | 17.4 | 15.8 | 16.3 | 16.0 | 16.4 |
| 26 | 19.2 | 18.6 | 16.7 | 18.5 | 17.4 | 17.2 | 16.8 | 17.3 | 18.4 | 18.5 |
| 27 | 19.5 | 18.7 | 23.3 | 20.9 | 23.9 | 24.6 | 23.4 | 23.9 | 20.5 | 20.7 |
| 28 | 28.9 | 28.9 | 69.6 | 28.8 | 176.3 | 177.1 | 69.9 | 70.5 | 28.7 | 28.7 |
| 29 | 16.8 | 17.5 | 16.9 | 16.6 | 17.5 | 27.1 | 17.5 | 17.8 | 17.0 | 17.0 |
| 30 | 21.0 | 21.2 | 66.3 | 21.0 | 21.4 | 16.7 | 21.4 | 21.6 | 65.9 | 65.9 |
| OCOPh | 165.5 | 165.6 | ||||||||
| iso | 131.0 | 131.0 | ||||||||
| orto | 129.5 | 129.5 | ||||||||
| meta | 128.8 | 128.4 | ||||||||
| para | 132.9 | 132.8 | ||||||||
| 1′ | 93.7 | 93.8 | 127.2 | 127.3 | ||||||
| 2′ | 79.2 | 79.1 | 114.0 | 129.5 | ||||||
| 3′ | 78.9 | 79.1 | 144.8 | 115.8 | ||||||
| 4′ | 70.7 | 70.8 | 147.2 | 157.4 | ||||||
| 5′ | 79.2 | 79.2 | 115.3 | 115.8 | ||||||
| 6′ | 62.1 | 62.2 | 122.1 | 129.5 | ||||||
| 7′ | 150.0 | 143.8 | ||||||||
| 8′ | 115.7 | 116.4 | ||||||||
| 9′ | 167.9 | 167.2 | ||||||||
| 1″ | 104.8 | 104.7 | ||||||||
| 2″ | 76.0 | 75.9 | ||||||||
| 3″ | 78.4 | 78.4 | ||||||||
| 4″ | 72.7 | 72.9 | ||||||||
| 5″ | 78.3 | 78.3 | ||||||||
| 6″ | 63.7 | 63.9 | ||||||||
| Ref | [54] | [54] | [185] | [193] | [194] | [194] | [231] | [204] | [185] | [185] |
| C | U42 | U43 | U44 | U45 | U46 | U47 | U48 | U49 | U50 | U51 a |
| 1 | 40.5 | 40.7 | 41.7 | 38.7 | 38.5 | 38.7 | 39.0 | 39.3 | 38.9 | 39.8 |
| 2 | 28.2 | 28.2 | 28.3 | 27.0 | 27.8 | 27.0 | 27.6 | 27.2 | 27.6 | 28.1 |
| 3 | 76.9 | 76.9 | 77.9 | 78.6 | 76.9 | 78.6 | 80.5 | 78.7 | 80.6 | 77.9 |
| 4 | 52.8 | 52.8 | 49.3 | 38.8 | 52.7 | 38.8 | 43.0 | 39.0 | 43.1 | 39.8 |
| 5 | 56.2 | 56.2 | 56.3 | 55.1 | 56.2 | 55.1 | 55.2 | 54.6 | 55.5 | 55.3 |
| 6 | 18.6 | 18.5 | 20.2 | 18.6 | 18.7 | 18.6 | 17.8 | 17.7 | 17.6 | 18.0 |
| 7 | 37.1 | 37.2 | 37.3 | 39.1 | 39.0 | 39.2 | 36.4 | 36.2 | 33.2 | 33.2 |
| 8 | 43.6 | 43.7 | 43.8 | 38.2 | 38.3 | 38.2 | 46.7 | 46.7 | 45.5 | 45.7 |
| 9 | 52.6 | 52.9 | 53.3 | 58.0 | 56.7 | 57.9 | 59.7 | 59.8 | 59.7 | 61.3 |
| 10 | 38.2 | 38.3 | 38.4 | 38.1 | 38.3 | 38.1 | 37.0 | 37.3 | 36.9 | 37.4 |
| 11 | 69.7 | 70.1 | 70.2 | 72.8 | 73.1 | 73.0 | 194.9 | 195.1 | 195.1 | 199.3 |
| 12 | 146.5 | 145.7 | 145.7 | 207.1 | 206.7 | 207.1 | 144.9 | 144.9 | 144.5 | 130.7 |
| 13 | 115.1 | 116.7 | 116.6 | 42.7 | 42.9 | 43.0 | 134.2 | 134.0 | 134.4 | 163.6 |
| 14 | 46.6 | 46.6 | 46.7 | 49.9 | 49.3 | 49.5 | 47.2 | 47.2 | 41.7 | 45.8 |
| 15 | 68.0 | 68.1 | 68.1 | 66.0 | 66.1 | 66.2 | 68.3 | 68.4 | 27.5 | 37.1 |
| 16 | 38.1 | 38.9 | 38.8 | 37.2 | 38.0 | 37.8 | 38.6 | 38.5 | 27.3 | 64.7 |
| 17 | 33.6 | 34.2 | 34.1 | 32.6 | 33.2 | 33.1 | 34.2 | 34.2 | 33.4 | 39.2 |
| 18 | 42.0 | 47.4 | 47.3 | 35.3 | 39.6 | 39.5 | 48.7 | 48.7 | 48.9 | 60.7 |
| 19 | 41.3 | 40.5 | 40.5 | 41.4 | 40.5 | 40.5 | 40.4 | 40.4 | 40.8 | 39.1 |
| 20 | 71.6 | 39.3 | 39.3 | 71.3 | 37.9 | 38.0 | 39.1 | 39.1 | 39.3 | 39.4 |
| 21 | 35.6 | 31.0 | 31.0 | 35.2 | 30.8 | 30.8 | 30.9 | 30.9 | 31.2 | 30.8 |
| 22 | 35.7 | 41.0 | 41.0 | 36.0 | 41.5 | 41.5 | 40.7 | 40.7 | 41.1 | 35.4 |
| 23 | 19.3 | 19.3 | 23.8 | 27.8 | 19.2 | 27.9 | 22.4 | 28.0 | 22.4 | 28.7 |
| 24 | 207.8 | 207.9 | 178.4 | 15.3 | 207.1 | 15.2 | 64.3 | 15.6 | 64.3 | 16.6 |
| 25 | 15.8 | 15.8 | 14.4 | 17.3 | 16.2 | 17.3 | 17.1 | 16.6 | 17.1 | 17.0 |
| 26 | 18.7 | 18.6 | 18.5 | 21.2 | 20.9 | 21.1 | 19.0 | 19.1 | 18.4 | 18.7 |
| 27 | 17.7 | 18.0 | 17.8 | 18.1 | 17.7 | 17.9 | 15.2 | 15.3 | 20.9 | 21.9 |
| 28 | 29.0 | 29.3 | 29.3 | 27.9 | 28.2 | 28.2 | 29.4 | 29.4 | 28.8 | 23.0 |
| 29 | 11.4 | 16.8 | 16.7 | 11.7 | 16.6 | 16.6 | 16.6 | 16.5 | 16.5 | 17.6 |
| 30 | 29.9 | 21.1 | 21.0 | 29.1 | 20.5 | 20.5 | 20.9 | 20.9 | 21.0 | 21.2 |
| OCH3 | 51.3 | |||||||||
| Ref | [193] | [54] | [54] | [193] | [193] | [193] | [193] | [54] | [54] | [190] |
| C | U52 a | U54 | U55 | U56 | U57 c | U58 | U59 | U60 | U62 | U63 a |
| 1 | 38.5 | 39.2 | 38.4 | 38.1 | 37.9 | 38.6 | 38.5 | 38.1 | 38.5 | 40.5 |
| 2 | 27.6 | 27.3 | 27.5 | 23.4 | 28.7 | 23.8 | 23.7 | 26.8 | 23.6 | 36.1 |
| 3 | 72.8 | 78.8 | 78.0 | 80.7 | 80.0 | 81.2 | 80.6 | 78.5 | 80.6 | 216.0 |
| 4 | 43.1 | 39.1 | 42.3 | 37.9 | 42.8 | 37.9 | 37.8 | 38.7 | 37.7 | 54.7 |
| 5 | 48.1 | 54.8 | 54.6 | 55.0 | 52.5 | 55.5 | 55.3 | 54.6 | 55.3 | 49.2 |
| 6 | 17.9 | 17.5 | 19.3 | 17.7 | 18.5 | 18.4 | 18.3 | 17.5 | 18.2 | 67.8 |
| 7 | 33.0 | 32.8 | 33.3 | 31.4 | 33.3 | 33.1 | 32.9 | 31.0 | 32.9 | 41.6 |
| 8 | 42.1 | 45.1 | 40.9 | 41.8 | 39.9 | 40.2 | 40.1 | 41.5 | 40.0 | 42.6 |
| 9 | 48.9 | 61.6 | 51.1 | 53.0 | 48.7 | 47.8 | 47.7 | 52.8 | 47.6 | 46.6 |
| 10 | 37.0 | 36.9 | 31.0 | 36.4 | 37.1 | 37.0 | 36.8 | 36.1 | 36.8 | 37.8 |
| 11 | 37.4 | 199.8 | 73.3 | 133.4 | 24.4 | 23.6 | 23.4 | 128.6 | 23.4 | 77.3 |
| 12 | 209.8 | 130.7 | 126.0 | 129.0 | 128.0 | 124.5 | 124.4 | 133.2 | 124.3 | 145.0 |
| 13 | 89.4 | 164.3 | 140.4 | 89.7 | 140.2 | 139.8 | 139.7 | 89.5 | 139.6 | 116.5 |
| 14 | 45.9 | 43.6 | 42.5 | 42.0 | 41.7 | 42.4 | 42.1 | 41.7 | 42.1 | 41.4 |
| 15 | 26.3 | 27.1 | 28.4 | 25.6 | 30.6 | 28.3 | 26.6 | 25.3 | 26.6 | 27.6 |
| 16 | 26.4 | 27.5 | 26.0 | 30.9 | 27.6 | 26.8 | 28.1 | 22.6 | 28.1 | 28.0 |
| 17 | 42.7 | 33.8 | 47.8 | 45.2 | 47.0 | 33.9 | 33.8 | 44.9 | 33.7 | 33.7 |
| 18 | 55.0 | 58.8 | 53.5 | 40.4 | 54.6 | 59.3 | 59.1 | 60.4 | 59.1 | 47.5 |
| 19 | 38.0 | 33.5 | 72.1 | 38.2 | 72.4 | 39.8 | 39.6 | 37.9 | 39.6 | 41.3 |
| 20 | 40.7 | 46.5 | 42.5 | 60.7 | 39.7 | 39.8 | 39.7 | 40.1 | 39.7 | 40.0 |
| 21 | 31.6 | 24.9 | 27.4 | 22.9 | 26.8 | 31.5 | 31.3 | 30.6 | 31.2 | 31.6 |
| 22 | 34.9 | 40.5 | 38.3 | 31.3 | 38.5 | 41.7 | 41.6 | 31.1 | 41.5 | 42.2 |
| 23 | 67.2 | 28.0 | 180.6 | 27.8 | 68.4 | 28.3 | 28.1 | 27.6 | 28.1 | 66.8 |
| 24 | 12.9 | 22.1 | 13.7 | 16.1 | 12.8 | 16.9 | 16.8 | 14.7 | 16.8 | 20.5 |
| 25 | 16.1 | 16.5 | 16.7 | 19.2 | 17.0 | 16.0 | 15.7 | 17.7 | 15.7 | 17.6 |
| 26 | 18.7 | 18.5 | 16.9 | 19.0 | 16.8 | 17.7 | 16.9 | 18.7 | 16.9 | 20.3 |
| 27 | 17.7 | 20.6 | 23.9 | 16.2 | 25.0 | 23.4 | 23.3 | 15.9 | 23.2 | 24.0 |
| 28 | 77.2 | 28.7 | 68.7 | 18.1 | 64.5 | 29.1 | 28.8 | 179.6 | 28.7 | 28.9 |
| 29 | 19.1 | 17.0 | 17.4 | 17.9 | 27.1 | 17.0 | 17.5 | 17.6 | 17.5 | 17.4 |
| 30 | 19.8 | 65.9 | 28.6 | 179.9 | 16.2 | 21.6 | 21.4 | 18.9 | 21.4 | 21.5 |
| OCH3 | 55.4 | 51.4 | ||||||||
| OCH3 | 21.7 | 21.4 | 21.2 | 21.5 | ||||||
| C=O | 170.4 | 171.1 | 169.9 | 171.5 | 173.5 | 173.7 | ||||
| 2′ | 34.9 | 34.9 | ||||||||
| 3′ | 25.2 | 25.2 | ||||||||
| 4′–13′ | 29.2–29.7 | 29.2–29.5 | ||||||||
| 14′ | 29.7 | 31.9 | ||||||||
| 15′ | 29.5 | 22.7 | ||||||||
| 16′ | 31.9 | 14.1 | ||||||||
| 17′ | 22.7 | |||||||||
| 18′ | 14.1 | |||||||||
| Ref | [189] | [185] | [232] | [233] | [232] | [234] | [235] | [236] | [6] | [190] |
| C | U64 c | U65 | U66 a | U67 | U68 | U69 a | U71 | U72 | U73c | U74 |
| 1 | 38.9 | 43.0 | 39.4 | 39.5 | 39.5 | 48.0 | 39.7 | 33.6 | 34.1 | 38.4 |
| 2 | 29.3 | 175.5 | 34.8 | 34.2 | 34.2 | 68.6 | 34.1 | 25.8 | 25.7 | 26.8 |
| 3 | 208.1 | 207.7 | 216.2 | 217.9 | 217.8 | 83.7 | 217.3 | 74.2 | 76.3 | 77.4 |
| 4 | 47.2 | 50.7 | 47.4 | 47.5 | 47.5 | 39.9 | 47.7 | 37.4 | 42.6 | 38.4 |
| 5 | 55.6 | 47.7 | 55.2 | 55.3 | 55.3 | 55.9 | 55.2 | 48.1 | 54.1 | 54.8 |
| 6 | 19.8 | 20.4 | 19.8 | 19.7 | 19.7 | 18.9 | 18.6 | 17.1 | 19.0 | 18.2 |
| 7 | 34.0 | 32.1 | 32.5 | 32.3 | 32.4 | 33.5 | 32.4 | 32.9 | 33.2 | 32.3 |
| 8 | 40.2 | 40.0 | 40.3 | 40.2 | 40.1 | 40.1 | 44.5 | 44.6 | 41.3 | 39.6 |
| 9 | 46.6 | 40.4 | 47.1 | 46.9 | 46.9 | 47.0 | 60.7 | 61.2 | 48.1 | 47.2 |
| 10 | 37.5 | 42.3 | 36.7 | 36.7 | 36.7 | 38.5 | 36.1 | 37.2 | 37.4 | 38.4 |
| 11 | 24.5 | 23.8 | 23.8 | 23.7 | 23.7 | 23.8 | 199.5 | 199.3 | 73.1 | 23.0 |
| 12 | 127.9 | 125.1 | 125.2 | 125.5 | 125.8 | 125.5 | 130.7 | 130.3 | 127.3 | 124.8 |
| 13 | 138.8 | 139.1 | 139.3 | 138.0 | 137.9 | 139.3 | 163.5 | 163.3 | 139.4 | 138.0 |
| 14 | 42.0 | 42.7 | 43.1 | 42.6 | 42.2 | 42.6 | 43.8 | 43.6 | 43.1 | 42.2 |
| 15 | 28.7 | 26.5 | 26.5 | 26.3 | 25.9 | 28.7 | 28.5 | 28.3 | 27.7 | 25.5 |
| 16 | 26.6 | 29.2 | 21.4 | 27.5 | 23.3 | 24.9 | 23.7 | 23.9 | 25.9 | 20.3 |
| 17 | 48.4 | 35.2 | 39.7 | 38.0 | 37.9 | 48.1 | 47.7 | 47.0 | 48.9 | 36.4 |
| 18 | 54.3 | 58.6 | 58.3 | 52.8 | 53.0 | 53.6 | 52.8 | 52.8 | 54.5 | 57.2 |
| 19 | 73.2 | 38.4 | 34.8 | 34.0 | 34.1 | 39.4 | 38.6 | 38.1 | 71.9 | 33.6 |
| 20 | 41.8 | 47.1 | 51.2 | 45.1 | 51.8 | 39.5 | 38.6 | 38.4 | 44.0 | 49.7 |
| 21 | 27.0 | 71.8 | 34.4 | 32.4 | 25.1 | 31.0 | 30.3 | 30.1 | 27.2 | 33.1 |
| 22 | 39.1 | 50.3 | 77.6 | 74.8 | 34.3 | 37.5 | 36.7 | 36.0 | 38.6 | 76.7 |
| 23 | 23.5 | 23.9 | 26.7 | 26.7 | 26.7 | 29.4 | 26.6 | 28.8 | 177.4 | 28.0 |
| 24 | 181.1 | 19.5 * | 21.6 | 21.6 | 21.6 | 17.7 | 21.3 | 22.1 | 13.1 | 15.3 |
| 25 | 15.0 | 19.4 * | 15.4 | 15.5 | 15.5 | 17.0 | 15.5 | 16.0 | 16.4 | 15.7 |
| 26 | 17.0 | 16.9 | 16.9 | 16.8 | 16.8 | 17.5 | 19.0 | 18.7 | 17.7 | 16.4 |
| 27 | 25.3 | 22.9 | 23.8 | 23.8 | 23.5 | 23.9 | 20.9 | 20.4 | 25.2 | 23.1 |
| 28 | 65.4 | 28.4 | 25.2 | 21.7 | 69.3 | 179.9 | 180.0 | 180.0 | 179.7 | 24.3 |
| 29 | 26.9 | 17.4 | 19.0 | 18.5 | 18.0 | 17.5 | 17.0 | 16.5 | 27.7 | 17.9 |
| 30 | 16.8 | 15.8 | 178.2 | 182.1 | 181.6 | 21.4 | 21.0 | 20.4 | 17.9 | 177.0 |
| Ref | [232] | [54] | [129] | [61] | [61] | [157] | [185] | [185] | [232] | [237] |
| C | U75 | U76 | U77 d | U78 a | U79 | U80 | U81 | U82 | U83 a | U84 |
| 1 | 42.7 | 38.1 | 39.0 | 48.0 | 40.0 | 40.9 | 40.4 | 40.8 | 33.9 | 38.8 |
| 2 | 34.5 | 23.8 | 28.3 | 68.6 | 34.4 | 27.3 | 27.8 | 27.4 | 28.4 | 27.3 |
| 3 | 74.6 | 80.8 | 79.1 | 83.9 | NR | 78.5 | 80.6 | 78.7 | 78.8 | 79.0 |
| 4 | 45.4 | 37.5 | 39.2 | 39.8 | 47.9 | 39.0 | 43.0 | 39.0 | 38.9 | 38.8 |
| 5 | 49.9 | 55.1 | 55.5 | 56.1 | 55.6 | 54.8 | 55.8 | 54.9 | 55.4 | 55.4 |
| 6 | 19.3 | 18.0 | 18.6 | 19.0 | 19.0 | 18.5 | 18.4 | 18.5 | 18.1 | 18.4 |
| 7 | 66.9 | 32.7 | 33.3 | 33.6 | 32.4 | 37.0 | 33.9 | 36.7 | 33.2 | 32.9 |
| 8 | 40.9 | 39.3 | 38.9 | 40.7 | 43.9 | 44.1 | 42.7 | 44.6 | 40.3 | 39.4 |
| 9 | 48.9 | 47.3 | 47.8 | 47.9 | 60.9 | 54.4 | 54.4 | 55.7 | 48.6 | 47.8 |
| 10 | 39.1 | 36.9 | 37.1 | 38.5 | 36.8 | 38.2 | 37.8 | 38.2 | 41.4 | 37.2 |
| 11 | 24.6 | 23.4 | 23.6 | 24.2 | 199.2 | 69.9 | 70.1 | 68.1 | 25.2 | 23.4 |
| 12 | 126.7 | 125.5 | 125.8 | 128.2 | 130.5 | 145.7 | 144.7 | 129.8 | 125.7 | 125.0 |
| 13 | 139.7 | 137.8 | 138.5 | 139.5 | 165.5 | 117.0 | 115.8 | 143.5 | 138.9 | 138.0 |
| 14 | 43.3 | 41.6 | 42.3 | 42.1 | 45.1 | 46.5 | 40.9 | 47.7 | 42.3 | 42.8 |
| 15 | 29.2 | 27.9 | 27.0 | 29.8 | 29.8 | 68.2 | 26.9 | 68.0 | 26.7 | 29.2 |
| 16 | 25.3 | 23.9 | 24.5 | 26.8 | 27.4 | 38.7 | 27.6 | 38.8 | 28.2 | 22.6 |
| 17 | 48.6 | 47.8 | 48.1 | 48.6 | 34.3 | 34.1 | 33.2 | 34.0 | 33.7 | 36.8 |
| 18 | 54.4 | 52.3 | 53.1 | 54.5 | 59.2 | 47.3 | 47.7 | 58.3 | 59.0 | 54.1 |
| 19 | 40.4 | 38.8 | 39.4 | 72.7 | 39.4 | 40.5 | 40.8 | 39.1 | 34.1 | 38.9 |
| 20 | 40.4 | 38.7 | 39.7 | 42.2 | 39.4 | 39.3 | 39.5 | 39.2 | 47.3 | 39.4 |
| 21 | 31.8 | 30.4 | 30.9 | 25.9 | 31.0 | 31.0 | 31.2 | 30.9 | 25.3 | 30.7 |
| 22 | 38.1 | 36.5 | 37.2 | 37.5 | 41.0 | 41.1 | 41.5 | 40.9 | 41.2 | 30.6 |
| 23 | 23.1 | 27.9 | 28.3 | 29.4 | 26.5 | 28.2 | 22.6 | 28.2 | 29.0 | 28.1 |
| 24 | 65.9 | 16.9 | 17.1 | 17.6 | 21.6 | 15.6 | 64.4 | 15.6 | 16.1 | 15.4 |
| 25 | 17.4 | 15.5 | 15.7 | 17.4 | 15.9 | 16.7 | 17.3 | 16.8 | 61.0 | 15.6 |
| 26 | 21.6 | 16.5 | 15.9 | 16.7 | 18.5 | 18.6 | 17.9 | 18.6 | 17.4 | 16.9 |
| 27 | 24.1 | 23.9 | 23.8 | 24.7 | 20.6 | 18.2 | 24.1 | 17.2 | 23.7 | 23.4 |
| 28 | 181.6 | 184.0 | 181.1 | 177.0 | 29.0 | 29.3 | 28.7 | 29.3 | 28.7 | 69.7 |
| 29 | 17.6 | 16.8 | 17.3 | 27.0 | 17.6 | 16.8 | 16.7 | 17.5 | 17.1 | 16.2 |
| 30 | 17.7 | 21.0 | 21.5 | 17.0 | 21.3 | 21.1 | 21.1 | 21.3 | 65.9 | 21.3 |
| 1′ | 93.7 | |||||||||
| 2′ | 79.3 | |||||||||
| 3′ | 79.0 | |||||||||
| 4′ | 70.9 | |||||||||
| 5′ | 79.1 | |||||||||
| 6′ | 62.4 | |||||||||
| 1″ | 104.8 | |||||||||
| 2″ | 75.9 | |||||||||
| 3″ | 78.3 | |||||||||
| 4″ | 72.9 | |||||||||
| 5″ | 78.1 | |||||||||
| 6″ | 63.9 | |||||||||
| Ref | [238] | [239] | [240] | [241] | [242] | [54] | [193] | [54] | [243] | [244] |
| C | U85 | U86 | U88 | |||||||
| 1 | 38.8 | 37.7 | 36.8 | |||||||
| 2 | 27.4 | 27.1 | 25.2 | |||||||
| 3 | 79.0 | 79.1 | 78.2 | |||||||
| 4 | 38.8 | 38.7 | 38.4 | |||||||
| 5 | 55.3 | 55.4 | 50.7 | |||||||
| 6 | 18.4 | 18.8 | 17.9 | |||||||
| 7 | 34.6 | 41.8 | 31.6 | |||||||
| 8 | 41.0 | 38.9 | 40.2 | |||||||
| 9 | 50.5 | 49.2 | 154.0 | |||||||
| 10 | 37.2 | 37.9 | 38.2 | |||||||
| 11 | 22.2 | 17.4 | 114.9 | |||||||
| 12 | 24.7 | 32.2 | 122.5 | |||||||
| 13 | 135.4 | 40.0 | 140.7 | |||||||
| 14 | 45.0 | 159.2 | 42.6 | |||||||
| 15 | 26.8 | 116.3 | 27.8 | |||||||
| 16 | 38.9 | 40.6 | 25.7 | |||||||
| 17 | 34.0 | 33.9 | 33.2 | |||||||
| 18 | 136.4 | 60.4 | 56.8 | |||||||
| 19 | 36.7 | 35.4 | 38.5 | |||||||
| 20 | 35.0 | 36.5 | 38.9 | |||||||
| 21 | 23.7 | 28.5 | 30.7 | |||||||
| 22 | 36.3 | 38.5 | 40.9 | |||||||
| 23 | 28.1 | 28.0 | 28.2 | |||||||
| 24 | 15.5 | 15.5 | 16.9 | |||||||
| 25 | 16.3 | 15.2 | 17.1 | |||||||
| 26 | 17.8 | 26.3 | 21.6 | |||||||
| 27 | 21.9 | 19.4 | 24.9 | |||||||
| 28 | 28.3 | 37.0 | 29.2 | |||||||
| 29 | 23.1 | 27.5 | 17.1 | |||||||
| 30 | 20.5 | 22.5 | 21.0 | |||||||
| Ref | [245] | [245] | [246] |
Ref: References; * Values bearing the same superscript are interchangeable; NR: Not reported; Solvent CDCl3; a Pyridine-d5; b CD3OD; c CDCl3 + DMSO-d6; d CDCl3+CD3OD; 13C-NMR data of some compounds were not found. In these cases, the reported identification were performed by comparison of other physical data: U30, U53 [247], U70 (1H -NMR, IR, MS) [248] e U87 (m.p., [α]D, IR, 1H-NMR) [249].