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. Author manuscript; available in PMC: 2022 Nov 17.
Published in final edited form as: J Am Chem Soc. 2021 Nov 5;143(45):18952–18959. doi: 10.1021/jacs.1c07144

Figure 2. Site-selective alkylation of simple trialkylamines and novel disconnection.

Figure 2.

Reaction conditions: trialkylamine (3.0 eq.), olefin (1.0 eq.), Ir(ppy)2(dtbby)PF6 (1 mol%), Ph3SiSH (20 mol%), Tol (0.1 M), Blue LED (32W), 28 °C, 2–8 h. #2-tert-butyl-1,1,3,3-tetramethylguanidine (50 mol%) used as additive.*TPS-SH (5 mol%) and Dioxane (0.1 M) were used instead.