Table 2.

¹H and ¹³C NMR data of 1 in CDCl₃ at 298 K.

Position	δC, type	δH, mult. (J in Hz)	Position	δC, type	δH, mult. (J in Hz)
1	129.5, C		22′	167.4, C
2	130.9, C		23′	74.5, CH	5.29, qd (6.3, 3.1)
3	125.9	7.75, m	24′	17.5, CH3	1.23, d (6.3)
4	130.0, CH	7.44, dd (7.6, 0.9)	25′	163.1, C
5	128.5, C		26′	114.3, C
6	140.6, C		27′	128.6, CH	7.90, dd (7.9, 1.6)
7	144.7, C		28′	118.7, CH	6.81, dt (0.9, 7.9)
8	113.6, C		29′	133.6, CH	7.30, dt (1.6, 7.9)
9	178.9, C		30′	113.9, CH	6.67, dd (7.9, 0.9)
10	ND		31′	146.7, C
11	ND		1″	166.4, C
12	ND		2″	55.5, CH	4.69, dd (6.6, 2.7)
13	15.1, CH3	2.58, d (0.9)	NH-2″		7.64, d (6.6)
14	7.7, CH3	2.26, s	3″	168.6, C
1′	166.1, C		4″	58.6, CH	3.57, m
2′	54.7, CH	4.45, dd (6.4, 3.1)	NH-4″		7.75, m
NH-2′		7.38, d (6.4)	5″	31.8, CH	2.10, m
3′	168.7, C		6″	18.9, CH3	1.10, d (6.7)
4′	57.9, CH	3.56, m	7″	19.2, CH3	0.91, d (6.7)
NH-4′		8.28, d (5.4)	8″	ND
5′	31.0, CH	2.17, m	9″	47.5, CH2	3.82, m 3.75, m
6′	18.8, CH3	1.13, d (6.7)	10″	22.8, CH2	2.29, m 2.07, m
7′	19.1, CH3	0.87, d (6.7	11″	31.1, CH2	2.84, m 1.86, dd (11.9, 6.9)
8′	ND		12″	56.3, CH	5.95, d (9.2)
9′	60.5, CH2	4.49, d (13.4) 4.07, d (13.4)	13″	172.9, C
10′	76.8, C		14″	34.9, CH3	2.89, s
11′	43.1, CH2	2.94, m 2.25, m	15″	51.3, CH2	4.72, d (17.1) 3.65, d (17.1)
12′	56.7, CH	6.27, d (10.5)	16″	165.4, C
13′	173.1, C		17″	39.4, CH3	2.93, s
14′	35.1, CH3	2.93, s	18″	71.4, CH	2.70, m
15′	51.1, CH2	4.36, d (17.1) 3.58, d (17.1)	19″	27.0, CH	2.69, m
16′	166.3, C		20″	19.0, CH3	0.75, d (6.3)
17′	39.1, CH3	2.95, s	21″	21.7, CH3	0.98, d (6.0)
18′	71.3, CH	2.67, m	22″	167.2, C
19′	26.9, CH	2.65, m	23″	75.2, CH	5.22, qd (6.3, 2.7)
20′	19.0, CH3	0.75, d (6.8)	24″	17.9, CH3	1.30, d (6.3)
21′	21.6, CH3	0.96, d (6.4)

¹H 850 MHz and ¹³C NMR resonances inferred from HSQC and HMBC spectra.