Fig. 3. Solid-state structure of (tBuPBP)Pd(CH3) with thermal ellipsoids at 30% probability. Hydrogen atoms are omitted for clarity. Selected distances (Å) and angles (°): Pd(1)–B(1) 2.027(4), Pd(1)–C(1) 2.185(4), Pd(1)–P(1) 2.3030(8), Pd(1)–P(2) 2.3035(8), B(1)–Pd(1)–C(1) 178.09(15), B(1)–Pd(1)–P(1) 77.36(12), C(1)–Pd(1)–P(1) 103.49(10), B(1)–Pd(1)–P(2) 77.33(12), C(1)–Pd(1)–P(2) 102.02(10), P(1)–Pd(1)–P(2) 153.74(3).
