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Fig. 6. Representative traces for the insertion of CO2 into (tBuPBP)Pd(CH3) at 40 °C in C6D6 with 1 atm of CO2 showing (a) the concentrations of (tBuPBP)Pd(CH3) and (tBuPBP)Pd{OC(O)CH3} as a function of time and (b) the ln of the concentration of (tBuPBP)Pd(CH3) as a function of time.