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a) Classical Si-free and Si-mediated SuFEx click reactions; b) Exemplary connective SuFEx hubs for modular click chemistry; c) pKaH values of representative SuFEx catalysts; d) Example of the relationship between SuFExability and catalyst activity; e) The development of BTMG-HMDS mediated Accelerated SuFEx Click Chemistry (ASCC); direct coupling of aryl and alkyl alcohols with SuFExable hubs mediated by HMDS.
