Table 3.
C# | Compounds | [M − H]− (m/z) | HPP-Treated | Untreated | ||||
---|---|---|---|---|---|---|---|---|
F | E | IB | F | E | IB | |||
1 | p-Hydroxybenzoic acid | 137 | 1.4 ± 0.03 | 0.49 ± 0.08 | 1.35 ± 0.03 | 0.46 ± 0.06 | ||
2 | Cinnamic acid | 147 | 3.24 ± 0.28 * | 1.54 ± 0.22 | 2.58 ± 0.15 | 1.51 ± 0.16 | ||
3 | Protocatechuic acid | 153 | 3.69 ± 0.24 * | 1.39 ± 0.1 * | 2.05 ± 0.18 * | 2.68 ± 0.26 | 1.12 ± 0.08 | 1.46 ± 0.08 |
4 | p-Coumaric acid | 163 | 2.89 ± 0.08 | 1.38 ± 0.05 * | 2.88 ± 0.2 * | 2.81 ± 0.01 | 1.11 ± 0.1 | 1.8 ± 0.12 |
5 | Vanillic acid | 167 | 1.37 ± 0.12 | 0.73 ± 0.1 | 0.95 ± 0.06 | 0.7 ± 0.06 | 0.89 ± 0.1 | |
6 | Gallic acid | 169 | 3.22 ± 0.32 * | 0.89 ± 0.12 | 1.55 ± 0.15 | 2.48 ± 0.18 | 0.85 ± 0.1 | 1.51 ± 0.22 |
7 | Caffeic acid | 179 | 1.01 ± 0.09 | 1.02 ± 0.16 | ||||
8 | Homovanillic acid | 181 | 1.03 ± 0.06 | |||||
9 | Hydroxygallic acid | 187 | 3.25 ± 0.34 * | 0.53 ± 0.04 | 2.42 ± 0.18 * | 2.24 ± 0.26 | 0.51 ± 0.08 | 1.89 ± 0.12 |
10 | Isoferulic acid | 193 | 0.76 ± 0.15 | |||||
11 | Syringic acid | 197 | 2.55 ± 0.1 | 0.34 ± 0.1 | 1.34 ± 0.05 | 2.5 ± 0.08 | 0.34 ± 0.05 | 1.3 ± 0.08 |
12 | p-Coumaroyl glycolic acid | 221 | 0.25 ± 0.1 | 0.66 ± 0.18 | ||||
13 | Sinapinic acid | 223 | 2.5 ± 0.18 * | 0.57 ± 0.12 | 1.79 ± 0.2 | |||
14 | Ellagic acid | 301 | 1.66 ± 0.15 | 0.54 ± 0.15 | 2.13 ± 0.28 | 1.61 ± 0.1 | 0.51 ± 0.12 | 2.1 ± 0.24 |
15 | Chlorogenic acid | 353 | 2.47 ± 0.18 | 3.06 ± 0.08 * | 2.4 ± 0.05 | 2.46 ± 0.1 | ||
16 | Caffeoyl glucoside | 387 | 2.47 ± 0.12 | 2.41 ± 0.16 | ||||
17 | Chicoric acid | 473 | 0.73 ± 0.16 | |||||
18 | Catechin | 289 | 5.8 ± 0.58 * | 1.2 ± 0.08 * | 2.33 ± 0.32 | 4.38 ± 0.36 | 0.85 ± 0.1 | 2.33 ± 0.16 |
19 | Quercetin | 301 | 3.05 ± 0.32 | 0.73 ± 0.18 | 1.7 ± 0.2 | 3.02 ± 0.14 | 0.7 ± 0.06 | 1.66 ± 0.1 |
20 | p-Hydroxybenzaldehyde | 121 | 1.81 ± 0.08 | 0.72 ± 0.06 | 0.81 ± 0.18 | 1.75 ± 0.1 | 0.71 ± 0.12 | 0.75 ± 0.08 |
21 | p-Hydroxycoumarin | 161 | 0.8 ± 0.16 | |||||
22 | Scopoletin | 191 | 1.56 ± 0.16 | |||||
23 | Leachianol F | 471 | 0.63 ± 0.05 | |||||
Total | 44.58 | 10.56 | 25.92 | 33.97 | 7.86 | 20.67 | ||
Total phenolic content | 81.06 | 62.5 |
All data represent the mean of triplicates. * Indicates significant differences (p < 0.05) for the same phenolic fraction among treatments. F, free; E, esterified; IB, insoluble-bound.