Table A3.
Assignment of 13C and 1H chemical shifts of CY.
| Glycosyl Residues | H1 | H2 | H3 | H4 | H5a/H5 | H5b/6a | H6b | CH3 | CH3CO |
|---|---|---|---|---|---|---|---|---|---|
| C1 | C2 | C3 | C4 | C5 | C6 | ||||
| α-L-Araf-(1→ | 5.17 | 4.13 | 3.87 | 4.06 | 3.76 | 3.64 | |||
| 110.62 | 82.62 | 77.97 | 85.22 | 62.64 | |||||
| →5)-α-L-Araf-(1→ | 5.04 | 4.07 | 3.96 | 4.16 | 3.84 | 3.75 | |||
| 108.6 | 82.52 | 78.12 | 83.6 | 68.09 | |||||
| →4)-α-D-Glcp-(1→ | 5.31 | 3.5 | 3.86 | 3.55 | 3.76 | 3.73 | 3.76 | ||
| 100.88 | 72.75 | 74.53 | 77.98 | 72.45 | 61.73 | ||||
| Arap-(1→ | 5.09 | ||||||||
| 108.76 | |||||||||
| →6)-α-D-Glcp-(1→ | 4.89 | 3.48 | 3.63 | 3.44 | 3.83 | 3.9 | 3.66 | ||
| 99.14 | 72.84 | 74.7 | 70.98 | 71.44 | 66.79 | ||||
| →2,4)- α-L-Rhap-(1→ | 5.2 | 4.04 | 4.02 | 4.33 | 3.8 | 18 | |||
| 99.72 | 77.57 | 71.63 | 78.47 | 70.87 | 1.17 | ||||
| →3,4)-α-D-Glcp-(1→ | 4.95 | 3.8 | 4.03 | 4.36 | 4.7 | 18 | |||
| 99.14 | 70.75 | 77.48 | 80.11 | 72.97 | 1.17 | ||||
| →4)-α-D-GalAp-(1→ | 4.88 | 3.66 | 3.91 | 4.36 | 5.05 | 3.73 | 1.96 | ||
| 101.7 | 69.54 | 69.79 | 80.06 | 72.09 | 172.13 | 54.29 | 21.2 | ||
| →4)-α-D-GalAp-(1→ | 5.04 | 3.73 | 3.94 | 4.52 | 4.6 | ||||
| 101.87 | 69.8 | 70.1 | 80.78 | 72.92 | 176.24 | ||||
| α-D-Galp-(1→ | 5.04 | 3.73 | 3.94 | 4.03 | 4.6 | 3.66 | 3.75 | ||
| 101.87 | 69.8 | 70.1 | 71.74 | 72.92 | 62.77 | ||||
| →6)-β-D-Galp-(1→ | 4.37 | 3.44 | 3.58 | 3.86 | 3.88 | 3.61 | 3.83 | ||
| 104.9 | 72.16 | 73.93 | 74.96 | 69.87 | 76.1 | ||||
| →4)-β-D-Galp-(1→ | 4.56 | 3.6 | 3.7 | 4.08 | 3.65 | 3.74 | |||
| 105.74 | 73.12 | 74.61 | 79.05 | 75.81 | 62.11 |