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Extracted ion chromatogram of metabolites influenced by sodium chloride on the ZIC-c HILIC and BEH-amide columns. Citrulline and glutamine showed the increased MS responses of sodium adducts in plasma and salt sample (pure sodium chloride solution) versus neat sample (no sodium chloride). Tryptophan and adenosine showed the increased MS responses of chloride adducts in plasma and salt sample (pure sodium chloride solution) versus neat sample (no sodium chloride).
