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. 2022 Jan 18;10(2):44. doi: 10.3390/toxics10020044

Table 1.

List of main PFAS categories and subgroups.

Non-Polymeric PFAS
Perfluorinated PFAS Polyfluorinated PFAS
Subgroup Examples Subgroup Examples
Perfluoroalkyl acids (PFAAs)
Perfluoroalkane sulfonic acids & sulfonates (PFSAs)
Perfluoroalkane sulfnic acids (PFSIAs)
Perfluorocarboxylic acids & carboxylates (PFCAs)
Perfluoroalkyl phosphonic acids (PFPAs)
Perfluoroalkyl phosphinic acids (PFPIAs)
PFBS, PFHxS, PFOS
PFOSI
PFBA, PFHxA, PFOA
C8-PFPA
C8/C8-PFPiA
Fluorotelomer compounds (FT) 6:2 FTO, 8:2 FTI
Perfluoroalkane sulfonamido compounds
(Me/Et/Bu-FASAs)
Miscellaneous
MeFOSA, FOSE
4,8-Dioxa-3H-perfluorononanoate
Perfluoroalkyl ether acids (PFEAs) GenX, Adona, F-53B
Perfluoroalkane sulfonamides (FASA) FOSA
Perfluoroalkane sulfonyl fluorides (PASFs) PBSF, POSF
Perfluoroalkyl iodides (PFAIs) PFHxI
Perfluoroalkanoyl fluorides (PAFs) POF
Perfluoroalkyl aldehydes (PFALs) PFNAL
Polymeric PFAS
Subgroup Examples
Fluoropolymers PVDF, FEP, PFA, ETFE, PTFE (Teflon)
Side-chain Fluorinated Polymers Fluorinated urethane/acrylate/methacrylate/oxetane plolymers
Perfluoropolyethers (PFPEs) PFPE-BP, Fluorolink-PFPE

Classification of PFAS family substances adapted from Buck et al., 2011 [1] and OECD, 2013 (OECD/UNEP Global PFC Group, Synthesis paper on per- and polyfluorinated chemicals, PFCs, Environment, Health and Safety Directorate, OECD. Paris, 2013) [57].