Table 4.
Compound/Sample | E100 (60 °C) |
E100 (180 °C) |
E80 (60 °C) |
E80 (180 °C) |
E50 (60 °C) |
E50 (180 °C) |
W (60 °C) |
W (180 °C) |
---|---|---|---|---|---|---|---|---|
Phenolic acids (μg/g of dry extract) | ||||||||
Salicylic | <LOQ | <LOQ | <LOQ | <LOQ | <LOQ | <LOQ | <LOQ | <LOQ |
4-hydroxybenzoic | 340.5 ± 0.2 | 35.1 ± 1.2 | 260.0 ± 4.4 | <LOQ | 317.0 ± 1.8 | 9.1 ± 0.2 | 521.0 ± 3.8 | <LOQ |
Gentistic | <LOQ | <LOQ | <LOQ | <LOQ | N/D | <LOQ | N/D | <LOQ |
Protocatechuic | 92.1 ± 0.8 | 128.5 ± 1.7 | 86.5 ± 4.1 | 105.5 ± 2.0 | N/D | 79.2 ± 3.5 | N/D | 81.4 ± 3.9 |
p-coumaric | 97.8 ± 4.6 | 117.0 ± 0.0 | 135.0 ± 2.1 | 86.3 ± 2.4 | 157.5 ± 2.2 | 111.5 ± 1.9 | N/D | 144.5 ± 0.5 |
Vanillic | 25.3 ± 0.8 | <LOQ | <LOQ | N/D | N/D | N/D | <LOQ | N/D |
Gallic | <LOQ | N/D | <LOQ | <LOQ | <LOQ | <LOQ | <LOQ | <LOQ |
Caffeic | N/D | N/D | <LOQ | <LOQ | N/D | <LOQ | N/D | N/D |
Syringic | 27.1 ± 1.2 | 47.3 ± 0.4 | 77.9 ± 1.8 | <LOQ | N/D | <LOQ | N/D | 37.9 ± 1.8 |
Ferulic | N/D | N/D | N/D | N/D | N/D | N/D | N/D | <LOQ |
Flavonoids (µg/g of dry extract) | ||||||||
Astragalin | 132.5 ± 1.6 | 297.0 ± 0.5 | 288.0 ± 2.5 | 130.5 ± 4.9 | 109.5 ± 0.6 | 82.0 ± 3.9 | N/D | N/D |
Tiliroside | 514.0 ± 0.7 | 591.5 ± 0.6 | 1565.0 ± 0.5 | 205.5 ± 1.0 | 1237.5 ± 4.9 | 193.0 ± 1.5 | <LOQ | <LOQ |
Narcissin | 46.7 ± 2.2 | 80.4 ± 1.1 | 118.0 ± 3.6 | 59.1 ± 2.7 | 98.2 ± 4.8 | 54.8 ± 2.5 | 30.4 ± 0.3 | 26.2 ± 0.9 |
Rutin | <LOQ | <LOQ | <LOQ | <LOQ | <LOQ | <LOQ | <LOQ | <LOQ |
Quercetin | N/D | 248.5 ± 0.9 | 29.1 ± 1.3 | 296.5 ± 1.1 | N/D | 316.0 ± 0.9 | N/D | 2.7 ± 0.5 |
Kaempferol | <LOQ | 37.2 ± 0.6 | 21.5 ± 0.6 | 27.2 ± 0.0 | <LOQ | 36.3 ± 0.4 | <LOQ | <LOQ |
Isorhamnetin | <LOQ | 55.8 ± 0.4 | 12.8 ± 0.3 | 51.2 ± 2.1 | N/D | 61.7 ± 0.3 | N/D | <LOQ |
Apigenin | <LOQ | 14.3 ± 0.4 | <LOQ | 5.9 ± 0.2 | <LOQ | <LOQ | <LOQ | <LOQ |
Prunetin | 2.1 ± 0.1 | 2.4 ± 0.1 | 3.6 ± 0.2 | 3.5 ± 0.1 | 1.8 ± 0.0 | 1.9 ± 0.0 | 1.7 ± 0.0 | 1.7 ± 0.1 |
Luteolin | N/D | <LOQ | N/D | N/D | N/D | N/D | N/D | <LOQ |
Rhamnetin | <LOQ | <LOQ | <LOQ | <LOQ | <LOQ | <LOQ | <LOQ | <LOQ |