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Synthesis of amphiphilic triazine-phosphorus metallodendrons. Conditions: (i) n-C12H25NH2, CHCl3, NaOH (aq.), 90%; (ii) tyramine, toluene, 110 °C, 95%; (iii) K2CO3, acetonitrile, 0 °C, 60%; (iv) AB5, K2CO3, acetonitrile, 75 °C, 93%; (v) 2-hydrazinopyridine, THF, 60 °C, 85%; (vi) CuCl2 or AuCl3, DMF, 60 °C, 54% or 40%.
