Table 3.
Morphology, thermal transitions, and Rmic at 37 °C for various RP molar ratios. Transition temperatures are for CPE-containing formulations. Average standard deviation for transition temperatures is 0.6 °C; see SI.19 for all values.
RP | molar ratio | structure bare | Rt [Å] bare | structure +CPEs | Rt [Å] +CPEs | Tmic [°C] +CPEs | Tlow [°C] +CPEs | Tgel [°C] +CPEs |
---|---|---|---|---|---|---|---|---|
N/A | 0 | FCC | 112 | FCC | 144 | 27.7 | 23.3 | 31.9 |
25R4 | 0.5 | BCC | 97 | FCC | 150 | 35.6 | 24.9 | 40.8 |
25R4 | 1 | BCC | 98 | FCC | 148 | 36.0 | 26.9 | 42.7 |
25R4 | 2 | BCC | 94 | FCC | 118 | 33.2 | 26.6 | 39.8 |
31R1 | 0.5 | FCC | 113 | FCC | 144 | 29.9 | 22.5 | 37.0 |
31R1 | 1 | BCC | 109 | FCC | 122 | 27.0 | 19.7 | 33.0 |
31R1 | 2 | BCC | 107 | BCC | 120 | 23.8 | 16.6 | 28.4 |