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. Author manuscript; available in PMC: 2022 Feb 28.

Published in final edited form as: J Am Chem Soc. 2021 Aug 31;143(36):14458–14463. doi: 10.1021/jacs.1c07139

Table 1.

Comparison of E[Ni(II/I)]

Complexes	Redox-activity	E_1/2[Ni(II/I)] (V vs Fc⁺/Fc)
(Phen)Ni(Mes)Br³⁹	Yes	−1.50
(bpy)Ni(Mes)Br⁴⁰	Yes	−1.79
7	No	−2.12^a
(6,6′-^Mebpy)NiBr₂⁴¹	Yes	−1.26
8	No	−1.55^a
3	No	−1.46^a

^a

E_P/2.