. 2022 Feb 15;61(8):3527–3539. doi: 10.1021/acs.inorgchem.1c03492

Table 3. Selected Au–N and Au–C Bond Distances for Pristine CTCs Obtained with Different Ligands^a and Au–N and Au–C Bond Distances of the Relative Products Obtained by the Reaction of the CTCs with Iodine.

	CTC^BzI₂^b	CTC^carbI₂^c	CTC^carbI₄^c	CTC^carbI₆^c	CTC^MeI₄
Au(III)–N	1.913 (Au1–I)	2.052 (Au1–I)	2.072 (Au1–I)	2.082 (Au1–I)	2.051 (Au1–I)
Au(I)–N	2.013 (Au2)	2.072 (Au2)	2.095 (Au2–I)	2.086 (Au2–I)	2.070 (Au2–I)
Au(I)–N	2.063 (Au3)	2.052 (Au3)	2.012 (Au3)	2.074 (Au3–I)	2.054 (Au3)
Au(III)–C	1.964 (Au1–I)	2.032 (Au1–I)	2.022 (Au1–I)	2.032 (Au1–I)	2.006 (Au1–I)
Au(I)–C	2.024 (Au2)	2.022 (Au2)	2.012 (Au2–I)	2.000 (Au2–I)	2.004 (Au2–I)
Au(I)–C	2.005 (Au3)	1.972 (Au3)	2.065 (Au3)	2.065 (Au3–I)	1.989 (Au3)
	CTC^Bz^d	CTC^carb			CTC^Me
Au(I)–N	2.042	2.032			nd^e
	2.051
	2.036
Au(I)–C	1.978	2.000			nd^e
	1.998
	2.003

CTC^Me = [μ–Au-C²,N³-1-methyl-imidazolate]₃, CTC^Bz = [μ–Au-C²,N³-1-benzyl-imidazolate]₃, CTC^carb = [μ–Au-C²,N³- N-methyl-C-methoxy-carbonate]₃.

Data taken from ref (16).

Data taken from ref (14).

Data taken from ref (36)..

nd = not determined.

Table 3. Selected Au–N and Au–C Bond Distances for Pristine CTCs Obtained with Different Ligandsa and Au–N and Au–C Bond Distances of the Relative Products Obtained by the Reaction of the CTCs with Iodine.