. 2022 Feb 17;61(8):3458–3471. doi: 10.1021/acs.inorgchem.1c03379

Table 2. Distortion Angle Parameters Σ (Angular Deviation at the origin) and Θ (Trigonal Torsion Angle) for [MnL₁]X Complexes 1–5 at 100 K.

	ClO₄^– (1)	BF₄^– (2)	NO₃^– (3)	Br^– (4)	I^– (5)
Σ	61.67	59.61	53.21	39.12	57.43
Θ	233.83	225.89	202.41	141.41	214.87
spin state	S = 2	S = 2	mixed	S = 1	mixed

Table 2. Distortion Angle Parameters Σ (Angular Deviation at the origin) and Θ (Trigonal Torsion Angle) for [MnL1]X Complexes 1–5 at 100 K.