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. 2022 Jan 24;2(2):407–418. doi: 10.1021/jacsau.1c00460

Table 1. Extinction Coefficients (ε), Triplet Energies (E00), and Excited-State Lifetimes (τ) of Iridium Hydride Complexesa.

Ir compounds ε at 465 nm (M–1 cm–1) E00 (eV) τ (μs)
Ir1 2087 2.46 4.20
Ir2 4124 2.20 15.7
Ir3 6526 2.10 2.05
Ir4 1525 2.27 1.02
a

Excited-state lifetimes at 77 K were measured using TCSPC in 2-MeTHF glass with λexc = 406 nm.