Table 1. Extinction Coefficients (ε), Triplet Energies (E00), and Excited-State Lifetimes (τ) of Iridium Hydride Complexesa.
| Ir compounds | ε at 465 nm (M–1 cm–1) | E00 (eV) | τ (μs) |
|---|---|---|---|
| Ir1 | 2087 | 2.46 | 4.20 |
| Ir2 | 4124 | 2.20 | 15.7 |
| Ir3 | 6526 | 2.10 | 2.05 |
| Ir4 | 1525 | 2.27 | 1.02 |
Excited-state lifetimes at 77 K were measured using TCSPC in 2-MeTHF glass with λexc = 406 nm.